About: Vibrational spectroscopic study of the uranyl selenite mineral derriksite Cu4UO2(SeO3)2(OH)6.H2O     Goto   Sponge   NotDistinct   Permalink

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  • Raman spectrum of the mineral derriksite Cu4UO2(SeO3)2(OH)6.H2O was studied and complemented by the infrared spectrum of this mineral. Both spectra were interpreted and partly compared with the spectra of demesmaekerite, marthozite, larisaite, haynesite and piretite. Observed Raman and infrared bands were attributed to the (UO2)2+, (SeO3)2-, (OH)- and H2O vibrations. The presence of symmetrically distinct hydrogen bonded molecule of water of crystallization and hydrogen bonded symmetrically distinct hydroxyl ions was inferred from the spectra in the derriksite unit cell. Approximate U-O bond lengths in uranyl and O-H ... O hydrogen bond lengths were calculated from the Raman and infrared spectra of derriksite.
  • Raman spectrum of the mineral derriksite Cu4UO2(SeO3)2(OH)6.H2O was studied and complemented by the infrared spectrum of this mineral. Both spectra were interpreted and partly compared with the spectra of demesmaekerite, marthozite, larisaite, haynesite and piretite. Observed Raman and infrared bands were attributed to the (UO2)2+, (SeO3)2-, (OH)- and H2O vibrations. The presence of symmetrically distinct hydrogen bonded molecule of water of crystallization and hydrogen bonded symmetrically distinct hydroxyl ions was inferred from the spectra in the derriksite unit cell. Approximate U-O bond lengths in uranyl and O-H ... O hydrogen bond lengths were calculated from the Raman and infrared spectra of derriksite. (en)
Title
  • Vibrational spectroscopic study of the uranyl selenite mineral derriksite Cu4UO2(SeO3)2(OH)6.H2O
  • Vibrational spectroscopic study of the uranyl selenite mineral derriksite Cu4UO2(SeO3)2(OH)6.H2O (en)
skos:prefLabel
  • Vibrational spectroscopic study of the uranyl selenite mineral derriksite Cu4UO2(SeO3)2(OH)6.H2O
  • Vibrational spectroscopic study of the uranyl selenite mineral derriksite Cu4UO2(SeO3)2(OH)6.H2O (en)
skos:notation
  • RIV/00023272:_____/14:#0002417!RIV15-MK0-00023272
http://linked.open...avai/riv/aktivita
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  • V
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  • January
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  • 53347
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  • RIV/00023272:_____/14:#0002417
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  • derriksite; Raman spectroscopy; infrared spectroscopy; selenite (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [4823E9C482DC]
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  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
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  • 117
http://linked.open...iv/tvurceVysledku
  • Frost, Ray Leslie
  • Čejka, Jiří
  • Scholz, Ricardo
  • Xi, Yunfei
  • López, Andrés
  • Theiss, Frederick L.
http://linked.open...ain/vavai/riv/wos
  • 000328179900064
issn
  • 1386-1425
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.saa.2013.08.026
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