About: A vibrational spectroscopic study of the arsenate minerals cobaltkoritnigite and koritnigite     Goto   Sponge   NotDistinct   Permalink

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  • Raman spectra of two well-defined types of cobaltkoritnigite and koritnigite crystals were recorded and interpreted. Significant differences in the Raman spectra of cobaltkoritnigite and koritnigite were observed. Observed Raman bands were attributed to the (AsO3OH)2 stretching and bending vibrations, stretching and bending vibrations of water molecules and hydroxyl ions. Both Raman and infrared spectra of cobaltkoritnigite identify bands which are attributable to phosphate and hydrogen phosphate anions proving some substitution of phosphate for arsenate in the structure of cobaltkoritnigite. The O-H ... O hydrogen bond lengths in the crystal structure of koritnigite were inferred from the Raman spectra and compared with those derived from the X-ray single crystal refinement.
  • Raman spectra of two well-defined types of cobaltkoritnigite and koritnigite crystals were recorded and interpreted. Significant differences in the Raman spectra of cobaltkoritnigite and koritnigite were observed. Observed Raman bands were attributed to the (AsO3OH)2 stretching and bending vibrations, stretching and bending vibrations of water molecules and hydroxyl ions. Both Raman and infrared spectra of cobaltkoritnigite identify bands which are attributable to phosphate and hydrogen phosphate anions proving some substitution of phosphate for arsenate in the structure of cobaltkoritnigite. The O-H ... O hydrogen bond lengths in the crystal structure of koritnigite were inferred from the Raman spectra and compared with those derived from the X-ray single crystal refinement. (en)
Title
  • A vibrational spectroscopic study of the arsenate minerals cobaltkoritnigite and koritnigite
  • A vibrational spectroscopic study of the arsenate minerals cobaltkoritnigite and koritnigite (en)
skos:prefLabel
  • A vibrational spectroscopic study of the arsenate minerals cobaltkoritnigite and koritnigite
  • A vibrational spectroscopic study of the arsenate minerals cobaltkoritnigite and koritnigite (en)
skos:notation
  • RIV/00023272:_____/14:#0002415!RIV15-MK0-00023272
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • V
http://linked.open...iv/cisloPeriodika
  • May
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  • 1276
http://linked.open...ai/riv/idVysledku
  • RIV/00023272:_____/14:#0002415
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  • koritnigite; cobaltokoritnigite; arsenates; Raman spectroscopy (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [B5B7A9BC2FA6]
http://linked.open...i/riv/nazevZdroje
  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
http://linked.open...in/vavai/riv/obor
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  • 125
http://linked.open...iv/tvurceVysledku
  • Frost, Ray Leslie
  • Sejkora, Jiří
  • Čejka, Jiří
  • Scholz, Ricardo
  • Xi, Yunfei
  • Cristiano, Lana
  • López, Andrés
  • Souza, Larissa
http://linked.open...ain/vavai/riv/wos
  • 000334898700040
issn
  • 1386-1425
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.saa.2014.01.106
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