About: A Raman spectroscopic study of hydrated molybdate mineral ferrimolybdite, Fe2(MoO4)3.7-8H2O     Goto   Sponge   NotDistinct   Permalink

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  • Raman spectra of two well-defined ferrimolybdite samples, Fe2(MoO4)3. 7-8H2O, from the Krupka deposit (northern Bohemia, Czech Republic) and Hurky near Rakovnik occurrence (central Bohemia, Czech Republic) were studied and tentatively interpreted. Observed bands were assigned to the stretching and bending vibrations of molybdate anions, Fe-O units and water molecules. Number of Raman and infrared bands assigned to (MoO4) units and water molecules proved that symmetrically (structurally) nonequivalent (MoO4) and H2O are present in the crystal structure of ferrimolybdite. Approximate O-H ... O hydrogen bond lengths (2.80-2.73 angstrom) were inferred from the published infrared spectra.
  • Raman spectra of two well-defined ferrimolybdite samples, Fe2(MoO4)3. 7-8H2O, from the Krupka deposit (northern Bohemia, Czech Republic) and Hurky near Rakovnik occurrence (central Bohemia, Czech Republic) were studied and tentatively interpreted. Observed bands were assigned to the stretching and bending vibrations of molybdate anions, Fe-O units and water molecules. Number of Raman and infrared bands assigned to (MoO4) units and water molecules proved that symmetrically (structurally) nonequivalent (MoO4) and H2O are present in the crystal structure of ferrimolybdite. Approximate O-H ... O hydrogen bond lengths (2.80-2.73 angstrom) were inferred from the published infrared spectra. (en)
Title
  • A Raman spectroscopic study of hydrated molybdate mineral ferrimolybdite, Fe2(MoO4)3.7-8H2O
  • A Raman spectroscopic study of hydrated molybdate mineral ferrimolybdite, Fe2(MoO4)3.7-8H2O (en)
skos:prefLabel
  • A Raman spectroscopic study of hydrated molybdate mineral ferrimolybdite, Fe2(MoO4)3.7-8H2O
  • A Raman spectroscopic study of hydrated molybdate mineral ferrimolybdite, Fe2(MoO4)3.7-8H2O (en)
skos:notation
  • RIV/00023272:_____/14:#0002394!RIV15-MK0-00023272
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  • 1085
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  • RIV/00023272:_____/14:#0002394
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  • ferrimolybdite; Raman spectroscopy; molybdate; water molecules (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [D67AD6E17620]
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  • Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
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  • 130
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  • Frost, Ray Leslie
  • Sejkora, Jiří
  • Čejka, Jiří
  • Malíková, Radana
  • Xi, Yunfei
  • López, Andrés
http://linked.open...ain/vavai/riv/wos
  • 000338806800013
issn
  • 1386-1425
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  • 10.1016/j.saa.2014.03.112
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