About: A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite

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About: A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Raman and infrared spectra of two polymorphous minerals with the chemical formula Fe3+(SO4)(OH). 2H2O, monoclinic butlerite and orthorhombic parabutlerite, are studied and the spectra assigned. Observed bands are attributed to the (SO4)2- stretching and bending vibrations, hydrogen bonded water molecules, stretching and bending vibrations of hydroxyl ions, water librational modes, Fe-O and Fe-OH stretching vibrations, Fe-OH bending vibrations and lattice vibrations. The O-H ... O hydrogen bond lengths in the structures of both minerals are calculated from the wavenumbers of the stretching vibrations. One symmetrically distinct (SO4)2- unit in the structure of butlerite and two symmetrically distinct (SO4)2- units in the structure of parabutlerite are inferred from the Raman and infrared spectra. This conclusion agrees with the published crystal structures of both mineral phases. Raman and infrared spectra of two polymorphous minerals with the chemical formula Fe3+(SO4)(OH). 2H2O, monoclinic butlerite and orthorhombic parabutlerite, are studied and the spectra assigned. Observed bands are attributed to the (SO4)2- stretching and bending vibrations, hydrogen bonded water molecules, stretching and bending vibrations of hydroxyl ions, water librational modes, Fe-O and Fe-OH stretching vibrations, Fe-OH bending vibrations and lattice vibrations. The O-H ... O hydrogen bond lengths in the structures of both minerals are calculated from the wavenumbers of the stretching vibrations. One symmetrically distinct (SO4)2- unit in the structure of butlerite and two symmetrically distinct (SO4)2- units in the structure of parabutlerite are inferred from the Raman and infrared spectra. This conclusion agrees with the published crystal structures of both mineral phases. (en)
Title	A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite (en)
skos:prefLabel	A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite (en)
skos:notation	RIV/00023272:_____/11:#0001564!RIV12-MK0-00023272
http://linked.open...avai/predkladatel	Národní muzeum
http://linked.open...avai/riv/aktivita	I Z
http://linked.open...avai/riv/aktivity	I, Z(MK00002327201)
http://linked.open...iv/cisloPeriodika	5
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Čejka, Jiří Plášil, Jakub Sejkora, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Národní muzeum
http://linked.open...dnocenehoVysledku	184251
http://linked.open...ai/riv/idVysledku	RIV/00023272:_____/11:#0001564
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	butlerite; parabutlerite; iron (III) sulfates; Raman spectroscopy; Infrared spectroscopy (en)
http://linked.open.../riv/klicoveSlovo	Infrared spectroscopy Raman spectroscopy butlerite iron (III) sulfates parabutlerite
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[B0C3E2FEB775]
http://linked.open...i/riv/nazevZdroje	Spectrochimica Acta Part A-Molecular and biomolecular spectroscopy
http://linked.open...in/vavai/riv/obor	DB
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	79
http://linked.open...iv/tvurceVysledku	Bahfenne, Silmarilly Frost, Ray Leslie Palmer, Sara J. Plášil, Jakub Sejkora, Jiří Čejka, Jiří
http://linked.open...ain/vavai/riv/wos	000293363000076
http://linked.open...n/vavai/riv/zamer	Vědecké zhodnocení a rozšiřování přírodovědeckého sbírkového fondu Národního muzea
issn	1386-1425
number of pages	8 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.saa.2011.04.069
is http://linked.open...avai/riv/vysledek of	A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite

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