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| rdf:type
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| Description
| - Raman spectroscopy has been used to study vanadates in the solid state. The molecular structure of the vanadate minerals vesignieite [BaCu3(VO4)2(OH)2] and volborthite [Cu3V2O7(OH)2. 2H2O] have been studied by Raman spectroscopy and infrared spectroscopy. The spectra are related to the structure of the two minerals. The Raman spectrum of vesignieite is characterized by two intense bands at 821 and 856 cm-1 assigned to nu1 (VO4)3- symmetric stretching modes. A series of infrared bands at 755, 787 and 899 cm-1 are assigned to the nu3 (VO4)3- antisymmetric stretching vibrational mode. Raman bands at 307 and 332 cm-1 and at 466 and 511 cm-1 are assigned to the nu2 and nu4 (VO4)3- bending modes. The Raman spectrum of volborthite is characterized by the strong band at 888 cm-1, assigned to the nu1 (VO3) symmetric stretching vibrations. Raman bands at 858 and 749 cm-1 are assigned to the nu3 (VO3) antisymmetric stretching vibrations; those at 814 cm-1 to the nu3 (VOV) antisymmetric vibrations; that at 508 cm-1 to the nu1 (VOV) symmetric stretching vibration and those at 442 and 476 cm-1 and 347 and 308 cm-1 to the nu4 (VO3) and nu2 (VO3) bending vibrations, respectively. The spectra of vesignieite and volborthite are similar, especially in the region of skeletal vibrations, even though their crystal structures differ.
- Raman spectroscopy has been used to study vanadates in the solid state. The molecular structure of the vanadate minerals vesignieite [BaCu3(VO4)2(OH)2] and volborthite [Cu3V2O7(OH)2. 2H2O] have been studied by Raman spectroscopy and infrared spectroscopy. The spectra are related to the structure of the two minerals. The Raman spectrum of vesignieite is characterized by two intense bands at 821 and 856 cm-1 assigned to nu1 (VO4)3- symmetric stretching modes. A series of infrared bands at 755, 787 and 899 cm-1 are assigned to the nu3 (VO4)3- antisymmetric stretching vibrational mode. Raman bands at 307 and 332 cm-1 and at 466 and 511 cm-1 are assigned to the nu2 and nu4 (VO4)3- bending modes. The Raman spectrum of volborthite is characterized by the strong band at 888 cm-1, assigned to the nu1 (VO3) symmetric stretching vibrations. Raman bands at 858 and 749 cm-1 are assigned to the nu3 (VO3) antisymmetric stretching vibrations; those at 814 cm-1 to the nu3 (VOV) antisymmetric vibrations; that at 508 cm-1 to the nu1 (VOV) symmetric stretching vibration and those at 442 and 476 cm-1 and 347 and 308 cm-1 to the nu4 (VO3) and nu2 (VO3) bending vibrations, respectively. The spectra of vesignieite and volborthite are similar, especially in the region of skeletal vibrations, even though their crystal structures differ. (en)
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| Title
| - A Raman spectroscopic study of the different vanadate groups in solid-state compounds - model case: mineral phases vesignieite [BaCu3(VO4)2(OH)2] and volborthite [Cu3V2O7(OH)2 .2H2O]
- A Raman spectroscopic study of the different vanadate groups in solid-state compounds - model case: mineral phases vesignieite [BaCu3(VO4)2(OH)2] and volborthite [Cu3V2O7(OH)2 .2H2O] (en)
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| skos:prefLabel
| - A Raman spectroscopic study of the different vanadate groups in solid-state compounds - model case: mineral phases vesignieite [BaCu3(VO4)2(OH)2] and volborthite [Cu3V2O7(OH)2 .2H2O]
- A Raman spectroscopic study of the different vanadate groups in solid-state compounds - model case: mineral phases vesignieite [BaCu3(VO4)2(OH)2] and volborthite [Cu3V2O7(OH)2 .2H2O] (en)
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| skos:notation
| - RIV/00023272:_____/11:#0001562!RIV12-MK0-00023272
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| http://linked.open...avai/predkladatel
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
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| http://linked.open...ai/riv/idVysledku
| - RIV/00023272:_____/11:#0001562
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| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - solid-state vanadates; vesignieite; volborthite; hydroxyl; Raman spectroscopy (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
| - Journal of Raman Spectroscopy
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| http://linked.open...in/vavai/riv/obor
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| http://linked.open...ichTvurcuVysledku
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| http://linked.open...cetTvurcuVysledku
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| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
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| http://linked.open...iv/tvurceVysledku
| - Bahfenne, Silmarilly
- Frost, Ray Leslie
- Keeffe, Eloise C.
- Palmer, Sara J.
- Plášil, Jakub
- Sejkora, Jiří
- Čejka, Jiří
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| http://linked.open...ain/vavai/riv/wos
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| http://linked.open...n/vavai/riv/zamer
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| issn
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| number of pages
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| http://bibframe.org/vocab/doi
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| is http://linked.open...avai/riv/vysledek
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