About: Raman spectroscopic study of the uranyl carbonate mineral cejkaite and its comparison with synthetic trigonal Na4[UO2(CO3)3]

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About: Raman spectroscopic study of the uranyl carbonate mineral cejkaite and its comparison with synthetic trigonal Na4[UO2(CO3)3] Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Raman and infrared spectroscopies were used to characterise two samples of triclinic cejkaite Na4[UO2(CO3)3] and its synthetic trigonal analogue. The nu3 (UO2)2+ mode is not Raman active, whereas both the nu3 and nu1 (UO2)2+ modes are infrared active. U-O bond lengths in uranyls were calculated from the spectra obtained and compared with bond lengths derived from crystal structure analyses. From the higher number of bands related to the uranyl and carbonate vibrations, the presence of symmetrically distinct (UO2)2+ and (CO3)2- units in both structures is proposed. Raman and infrared spectroscopies were used to characterise two samples of triclinic cejkaite Na4[UO2(CO3)3] and its synthetic trigonal analogue. The nu3 (UO2)2+ mode is not Raman active, whereas both the nu3 and nu1 (UO2)2+ modes are infrared active. U-O bond lengths in uranyls were calculated from the spectra obtained and compared with bond lengths derived from crystal structure analyses. From the higher number of bands related to the uranyl and carbonate vibrations, the presence of symmetrically distinct (UO2)2+ and (CO3)2- units in both structures is proposed. (en)
Title	Raman spectroscopic study of the uranyl carbonate mineral cejkaite and its comparison with synthetic trigonal Na4[UO2(CO3)3] Raman spectroscopic study of the uranyl carbonate mineral cejkaite and its comparison with synthetic trigonal Na4[UO2(CO3)3] (en)
skos:prefLabel	Raman spectroscopic study of the uranyl carbonate mineral cejkaite and its comparison with synthetic trigonal Na4[UO2(CO3)3] Raman spectroscopic study of the uranyl carbonate mineral cejkaite and its comparison with synthetic trigonal Na4[UO2(CO3)3] (en)
skos:notation	RIV/00023272:_____/10:#0001275!RIV11-MK0-00023272
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MK00002327201)
http://linked.open...iv/cisloPeriodika	4
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Čejka, Jiří Plášil, Jakub Sejkora, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Národní muzeum
http://linked.open...dnocenehoVysledku	283846
http://linked.open...ai/riv/idVysledku	RIV/00023272:_____/10:#0001275
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	cejkaite; uranyl; carbonate; Raman spectra; Infrared spectra (en)
http://linked.open.../riv/klicoveSlovo	carbonate uranyl Raman spectra Infrared spectra cejkaite
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[8A7EA9C0D4B7]
http://linked.open...i/riv/nazevZdroje	Journal of Raman Spectroscopy
http://linked.open...in/vavai/riv/obor	DB
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	41
http://linked.open...iv/tvurceVysledku	Bahfenne, Silmarilly Frost, Ray Leslie Palmer, Sara J. Plášil, Jakub Sejkora, Jiří Čejka, Jiří
http://linked.open...ain/vavai/riv/wos	000277344100015
http://linked.open...n/vavai/riv/zamer	Vědecké zhodnocení a rozšiřování přírodovědeckého sbírkového fondu Národního muzea
issn	0377-0486
number of pages	6 (xsd:int)
is http://linked.open...avai/riv/vysledek of	Raman spectroscopic study of the uranyl carbonate mineral cejkaite and its comparison with synthetic trigonal Na4[UO2(CO3)3] Raman spectroscopic study of the uranyl carbonate mineral cejkaite and its comparison with synthetic trigonal Na4[UO2(CO3)3] Raman spectroscopic study of the uranyl carbonate mineral cejkaite and its comparison with synthetic trigonal Na4[UO2(CO3)3]

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