About: Raman spectroscopic study of the uranyl selenite mineral marthozite Cu[(UO2)3(SeO3)2O2].8H2O     Goto   Sponge   NotDistinct   Permalink

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  • The mineral marthozite, a uranyl selenite, has been characterised by Raman spectroscopy at 298 K. The bands at 812 and 797 cm-1 were assigned to the symmetric stretching modes of the (UO2)2+ and (SeO3)2 units, respectively. These values gave the calculated U-O bond lengths in uranyl of 1.799 and/or 1.814 angstrom. Average U-O bond length in uranyl is 1.795 angstrom, inferred from the X-ray single crystal structure analysis of marthozite by Cooper and Hawthorne. The broad band at 869 cm-1 was assigned to the v(3) antisymmetric stretching mode of the (UO2)2+ (calculated U-O bond length 1.808 angstrom). The band at 739 cm-1 was attributed to the v(3) antisymmetric stretching vibration of the (SeO3)2- units. The v(4) and the v(2) vibrational modes of the (SeO3)2- units were observed at 424 and 473 cm-1.
  • The mineral marthozite, a uranyl selenite, has been characterised by Raman spectroscopy at 298 K. The bands at 812 and 797 cm-1 were assigned to the symmetric stretching modes of the (UO2)2+ and (SeO3)2 units, respectively. These values gave the calculated U-O bond lengths in uranyl of 1.799 and/or 1.814 angstrom. Average U-O bond length in uranyl is 1.795 angstrom, inferred from the X-ray single crystal structure analysis of marthozite by Cooper and Hawthorne. The broad band at 869 cm-1 was assigned to the v(3) antisymmetric stretching mode of the (UO2)2+ (calculated U-O bond length 1.808 angstrom). The band at 739 cm-1 was attributed to the v(3) antisymmetric stretching vibration of the (SeO3)2- units. The v(4) and the v(2) vibrational modes of the (SeO3)2- units were observed at 424 and 473 cm-1. (en)
Title
  • Raman spectroscopic study of the uranyl selenite mineral marthozite Cu[(UO2)3(SeO3)2O2].8H2O
  • Raman spectroscopic study of the uranyl selenite mineral marthozite Cu[(UO2)3(SeO3)2O2].8H2O (en)
skos:prefLabel
  • Raman spectroscopic study of the uranyl selenite mineral marthozite Cu[(UO2)3(SeO3)2O2].8H2O
  • Raman spectroscopic study of the uranyl selenite mineral marthozite Cu[(UO2)3(SeO3)2O2].8H2O (en)
skos:notation
  • RIV/00023272:_____/08:#0000996!RIV10-MK0-00023272
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • V
http://linked.open...iv/cisloPeriodika
  • 10
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 391441
http://linked.open...ai/riv/idVysledku
  • RIV/00023272:_____/08:#0000996
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • marthozite; uranyl minerals; selenites; Raman spectroscopy; mineralogy (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [10AD1CA53584]
http://linked.open...i/riv/nazevZdroje
  • Journal of Raman Spectroscopy
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 39
http://linked.open...iv/tvurceVysledku
  • Frost, Ray Leslie
  • Keeffe, Eloise C.
  • Čejka, Jiří
  • Dickfos, Marilla J.
http://linked.open...ain/vavai/riv/wos
  • 000260355900014
issn
  • 0377-0486
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