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  • Raman spectroscopy, complemented with infrared spectroscopy, was used to study the uranyl carbonate mineral voglite. The mineral has the formula Ca2Cu2+ [(UO2)(CO3)(3)](CO3)6H(2)O, and bands attributed to these vibrating units are readily identified in the Raman spectrum. Symmetric stretching modes at 836 and 1094 cm(-1) are assigned to nu(1)(UO2)(2+) and nu(1)(CO3)(2-) units, respectively. The nu(3) antisymmetric stretching modes of (UO2)(2+) are not observed in the Raman spectrum but may be readily observed in the infrared spectrum at 898 cm(-1). The nu(3) antisymmetric stretching mode of (CO3)(2-) is observed in the Raman spectrum at 1369 cm(-1) as a low intensity band as is also the nu(3)(CO3)(2-) infrared modes at 1362, 1425, 1509 and 1566 cm(-1). No nu(2)(CO3)(2-) Raman bending modes are observed for voglite.
  • Raman spectroscopy, complemented with infrared spectroscopy, was used to study the uranyl carbonate mineral voglite. The mineral has the formula Ca2Cu2+ [(UO2)(CO3)(3)](CO3)6H(2)O, and bands attributed to these vibrating units are readily identified in the Raman spectrum. Symmetric stretching modes at 836 and 1094 cm(-1) are assigned to nu(1)(UO2)(2+) and nu(1)(CO3)(2-) units, respectively. The nu(3) antisymmetric stretching modes of (UO2)(2+) are not observed in the Raman spectrum but may be readily observed in the infrared spectrum at 898 cm(-1). The nu(3) antisymmetric stretching mode of (CO3)(2-) is observed in the Raman spectrum at 1369 cm(-1) as a low intensity band as is also the nu(3)(CO3)(2-) infrared modes at 1362, 1425, 1509 and 1566 cm(-1). No nu(2)(CO3)(2-) Raman bending modes are observed for voglite. (en)
Title
  • Raman spectroscopic study of the uranyl carbonate mineral voglite
  • Raman spectroscopic study of the uranyl carbonate mineral voglite (en)
skos:prefLabel
  • Raman spectroscopic study of the uranyl carbonate mineral voglite
  • Raman spectroscopic study of the uranyl carbonate mineral voglite (en)
skos:notation
  • RIV/00023272:_____/08:#0000994!RIV10-MK0-00023272
http://linked.open...avai/riv/aktivita
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  • V
http://linked.open...iv/cisloPeriodika
  • 3
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...dnocenehoVysledku
  • 391437
http://linked.open...ai/riv/idVysledku
  • RIV/00023272:_____/08:#0000994
http://linked.open...riv/jazykVysledku
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  • uranyl carbonate; voglite; Jáchymov; mineralogy; Raman spectroscopy (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [650B5A743AAE]
http://linked.open...i/riv/nazevZdroje
  • Journal of Raman Spectroscopy
http://linked.open...in/vavai/riv/obor
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 39
http://linked.open...iv/tvurceVysledku
  • Frost, Ray Leslie
  • Čejka, Jiří
  • Ayoko, Godwin
  • Dickfos, Marilla J.
http://linked.open...ain/vavai/riv/wos
  • 000254586500011
issn
  • 0377-0486
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