About: New inorganic compounds and advanced materials

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Projekt, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	http://linked.opendata.cz/ontology/domain/vavai/Projekt
rdfs:seeAlso	http://www.isvav.cz/projectDetail.do?rowId=LN00A028
Description	Fundamental oriented research, inorganic, organometallic, organometalloid compounds and advanced materials (amorphous, glassy, crystalline) with potential application in chemistry, catalysis, electronics, optics, optoelectronics and in pharmacy.Amorphous, glassy chalcogenides and oxides, preparation, sol-gel method, thin films, nanoparticles, sputtering, optical, thermal and chemical properties, structure, reactivity, luminescence, catalytic and photoinduced effects, informations storage.Developed will be chemistry of metallocenes and organometallic Sn compounds, with emphasis on mono- and multinuclear complexes. Via recent methods, relations between static and dynamic (reactivity, catal. and biol. activity) properties will be explored.Via insertion and degradation reactions of the B-cage, new ways to new carboranes and Group 15 heteroboranes and heterocarboranes will be explored. Their metallaborane chemistry with emphasis on ferrocene analogues will be developed as well. (en) Základní cílený výzkum, anorganické, organometalické a organometaloidní sloučeniny a perspektivní materiály (amorfní, sklovité a krystalické) s potenciálním využitím v chemii, katalýze, elektronice, optice, optoelektronice a ve zdravotnictví.Amorfní a sklovité chalkogenidy a oxidy, příprava, metoda sol-gel, tenké vrstvy, nanočástice, naprašování, optické, termické a chemické vlastnosti, struktura, reaktivita, luminiscence, katalytické a fotoindukované jevy, zápis informacíBude rozvíjena chemie nových metalocenů a organokovových sloučenin Sn s důrazem na mono- a vícejaderné komplexy. Pomocí moderních metod budou sledovány vztahy mezi strukturou a statickými a dynamickými (reaktivita, katal. a biol. aktivita) vlastnostmi.Aplikací inserčních a degradačních reakcí B-skeletu budou hledány cesty přípravy nových typů karboranů, heteroboranů a heterokarboranů (obsahujících elementy skup. 15). Bude rozvíjena i jejich metalaboranová chemie s důrazem na analoga ferrocenu
Title	New inorganic compounds and advanced materials (en) Nové a perspektivní anorganické sloučeniny a materiály
skos:notation	LN00A028
http://linked.open...avai/cep/aktivita	Research centres
http://linked.open...kovaStatniPodpora	http://linked.opendata.cz/resource/domain/vavai/projekt/LN00A028/celkovaStatniPodpora
http://linked.open...ep/celkoveNaklady	http://linked.opendata.cz/resource/domain/vavai/projekt/LN00A028/celkoveNaklady
http://linked.open...datumDodatniDoRIV	2008-05-28 (xsd:date)
http://linked.open...i/cep/druhSouteze	VS - Veřejná soutěž ve výzkumu a vývoji
http://linked.open...ep/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open.../cep/fazeProjektu	1756945
http://linked.open...ai/cep/hlavniObor	CA - Anorganická chemie
http://linked.open...hodnoceniProjektu	V - Vynikající výsledky (s mezinárodním významem apod.). Zároveň byly splněny cíle a předpokládané výsledky uvedené ve smlouvě / rozhodnutí o poskytnutí podpory.
http://linked.open...vai/cep/kategorie	NV - Aplikovaný výzkum s výjimkou průmyslového výzkumu (tzv. %22neprůmyslový výzkum%22)
http://linked.open.../cep/klicovaSlova	Advanced materials; Inorganic compounds; Amorphous and glassy chalcogenides; oxides; semiconductors; metallorganic compounds; heteroboranes; carboranes; nanoparticles; structure; optical properties; magnetic properties; thermal properties; NMR (en)
http://linked.open...ep/partnetrHlavni	Fakulta chemicko-technologická
http://linked.open...inujicichPrijemcu	0 (xsd:int)
http://linked.open...cep/pocetPrijemcu	1 (xsd:int)
http://linked.open...ocetSpoluPrijemcu	1 (xsd:int)
http://linked.open.../pocetVysledkuRIV	268 (xsd:int)
http://linked.open...enychVysledkuVRIV	268 (xsd:int)
http://linked.open...okUkonceniPodpory	2004
http://linked.open...okZahajeniPodpory	2000
http://linked.open...iciPoslednihoRoku	2005
http://linked.open...atUdajeProjZameru	2005
http://linked.open.../vavai/cep/soutez	SMSM0031008
http://linked.open...usZobrazovaneFaze	DUU
http://linked.open...ai/cep/typPojektu	P - Projekt výzkumu a vývoje financovaný ze státního rozpočtu
http://linked.open.../cep/vedlejsiObor	BH - Optika, masery a lasery BM - Fyzika pevných látek a magnetismus
http://linked.open...jektu+dodavatelem	Advanced materials and compounds (amorphous chalcogenides, metallic oxides, nanomaterials, orgnometallics, organometalloids) with application in information technologies, in catalysis and medicine were prepared and studied. International and publications (en) Připraveny a prostudovány perspektivní sloučeniny a systémy (amorfní chalkogenidy, oxidy kovů, nanomateriály, organometallické a organometalloidní látky) s využitím v informačních technologiích, v katalyze, ve zdravotnictví. Zvýšena mezinárodní spoluprác (cs)
http://linked.open...tniCyklusProjektu	ZBBBKU
http://linked.open.../cep/klicoveSlovo	carboranes heteroboranes magnetic properties nanoparticles optical properties oxides semiconductors structure thermal properties Amorphous and glassy chalcogenides Inorganic compounds metallorganic compounds Advanced materials
is http://linked.open...vavai/riv/projekt of	Crystallization of Se and of As-Se and Ge-Se systems with low concentration of metal Copper intercalation into Bi2Te3 single crystals Metallacarborane chemistry of the hypho-[6,7-C2B6H13](-)1-anion: the formation of uniquely structured metallacarboranes [5-Cp-arachno-5,4,6-RhC2B6H12] and [2,5-Cp-2()-10-Me-nido-2,5,1-Rh2CB6H9] (Cp-* = eta(5)-C5Me5-): complete rhodium analogues of a... Microstructures of painting layers in the analysis of art pigments provenance Preparation of potassium tantalate thin films through chemical solution deposition Příprava destičkového ZnO jako pigmentu pro korozní ochranu kovů Ten-vertex polyhedral azametallaborane chemistry: a unique nido-6,9 to nido-6,8-cluster isomerization Adsorption of cesium on Czech smectite-rich clays - A comparative study Ligand field model for (C2v) metallocene complexes. D3 and d4 strong-field energy matrices Ligand field model and d-d spectra of dN metallocene complexes The Contribution to the Study of the Glass Transition Clay and iron oxide pigments in the history of painting. Comparison of photocatalytical properties of anatase and rutile TiO2 in degradation of 4-chlorophenol in aqueous solution. Cluster opening of nido-1-CB8H12 by Lewis bases. Inclusion Compounds of Vanadoce Dichloride and Cyclodextrines Insertion of sulphur into smaller carbaboranes and carbon into some thiaboranes Kauzmann temperature and the glass transition Krystalizace selenu a sklotvorných tavenin systémů MxSe100-x (M = As, Ge; x 8) Kompoziční závislosti optických parametrů iontů Sm3+ ve sklech Ge-Ga-Se Kinetics of optically-induced diffusion of silver in amorphous As33S33.5Se33.5 films and their optical properties and structure Li+induced sigma-bond metathesis: Aryl for methyl exchange on boron in a methylated monocarbadodecaborate anion Leaching of lead metallurgical slag in citric solutions - implications for disposal and weathering in soil environments Li(+)-catalyzed nucleophilic B-arylation on the monocarbadodecaborane cage Study on Glass Transition and Crystallization Kinetics of GexSb40-xSe60 Glasses by Differential Thermal Analysis. Structure and optical properties of Ge-Se amorphous films prepared by pulsed laser deposition Struktura a optické vlastnosti tenkých vrstev amorfních Ge-Ga-Se chalkogenidů připravených pulzní laserovou depozicí Stereochemistry of carboranes originating from a 7-step degradation of decaborane Study of the preparation of ruthenia based catalytic materials by heating their precursors Supramolecular variations based on cobalt bis(dicarbollide)(1-)ion Stereochemistry of carboranes originating from a 7-step degradation of decaborane Structure thermally and optically induced effects in amorphous As2Se3 films prepared by pulsed laser deposition The vibrational spectra of the dimethyltitanocene dihalides Two forgotten ten-vertex arachno triheteroboranes: arachno-5,6,9-C2SB7H11 and arachno-5,6,9-C3B7H13, their molecular structure determination by ab initio/nmr approach and synthesis of the thiacarbaborane. Two isomeric phosphacarboranes 2,1- and 6,1-PCB8H9, the first representatives of the 10-vertex closo phosphacarborane series. Ag Doped Chalcogenide Glasses and Their Applications Aerogel nanoscale aluminium oxides as a destructive sorbent for mustard gas Analysis of earthy pigments in grounds of Baroque paintings. Ag-Sb-S amorphous chalcogenide thin films prepared by optically induced dissolution and diffusion on silver Formation of two isomeric closo-[(eta(5)-C5H5)FePC2B8H10] phosphadicarbaborane analogues of ferrocene via isolable eta(1)-bonded complexes of the [7-{(eta(5)-C5H5)Fe(CO)(2)}-(eta(1)-nido-PC2B8H10)] type Expression of the Optical Constants of Chalcogenide Thin Films Using the New Parametrization Dispersion Model Fe2O3-Cr2O3 system revised. Emanation thermal analysis study of synthetic gibbsite - Evaluation of experimental ETA results by mathematical modelling. Elektrotechnická analýza tradičních uměleckých pigmentů a barviv. Fotokatalyticky aktivní TiO2 a samočisticí efekt. Non-isothermal Relaxation and the Glass Transition Temperature Non-isothrermal Structural Relaxation and the Glass Transition Temperature Optical properties and structure of amorphous Agx(As0.33S0.67)100-x films prepared by optically- induced diffusion and dissolution of silver into spin-coated amorphous As33S67 films On the effect of Composition on the Judd-Ofelt Parameters of Sm3+-doped Chalcogenide Glasses On the Optical Properties of Amorphous Ge-Ga-Se Films Prepared by Pulsed Laser Deposition New view on glass transition. Optically-induced Diffusion and Dissolution of Metals in Amorphous Chalcogenides

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