About: Anodic Photoreactions of Importance in Solar Cell Design and Waste Water Processing

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Projekt, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	http://linked.opendata.cz/ontology/domain/vavai/Projekt
rdfs:seeAlso	http://www.isvav.cz/projectDetail.do?rowId=GA203/93/0250
Description	Projekt je zaměřen na studium fotooxidace vybraných organických a anorganických látek na elektrodách a koloidních částicích z n-TiO2 (anatasu). Zkoumanými látkami budou. (i) elektrolyty a aprotická rozpouštědla, použitelná v regenerativních fotoelektrochemických solárních bateriích a (ii) modelové polutanty, vyskytující se v průmyslových a komunálních odpadních vodách. Oxidační degradace bude studována obvyklými fotochemickými, spektroskopickými, foto- a spektroelektrochemickými technikami. Důraz bude kaden na použití in-situ FTIR spektroskopie (SNIFTIRS) a identifikaci rozkladných produktů a reakčních mechanismů. Cílem je nalézt a vysvětlit faktory ovlivňující rychlost fotooxidace vybraných látek na n-TiO2. Materiály a systémy optimálních vlastností bdou testovány v praktických solárních bateriích a reaktorech pro čištění odpadních vod.
Title	Anodic Photoreactions of Importance in Solar Cell Design and Waste Water Processing (en) Anodické fotoreakce uplatňující se v solárních článcích a při čištění odpadních vod
skos:notation	GA203/93/0250
http://linked.open...avai/cep/aktivita	Standard projects
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http://linked.open...ep/celkoveNaklady	http://linked.opendata.cz/resource/domain/vavai/projekt/GA203%2F93%2F0250/celkoveNaklady
http://linked.open...ep/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open.../cep/fazeProjektu	150716
http://linked.open...ai/cep/hlavniObor	CF - Fyzikální chemie a teoretická chemie
http://linked.open...ep/partnetrHlavni	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...inujicichPrijemcu	0 (xsd:int)
http://linked.open...cep/pocetPrijemcu	1 (xsd:int)
http://linked.open...ocetSpoluPrijemcu	1 (xsd:int)
http://linked.open.../pocetVysledkuRIV	31 (xsd:int)
http://linked.open...enychVysledkuVRIV	31 (xsd:int)
http://linked.open...iciPoslednihoRoku	1996
http://linked.open...atUdajeProjZameru	1996
http://linked.open...usZobrazovaneFaze	DUU
http://linked.open...ai/cep/typPojektu	P - Projekt výzkumu a vývoje financovaný ze státního rozpočtu
http://linked.open.../cep/vedlejsiObor	DJ - Znečištění a kontrola vody CH - Jaderná a kvantová chemie, fotochemie
http://linked.open...jektu+dodavatelem	XXX (cs)
http://linked.open...tniCyklusProjektu	.BKU
is http://linked.open...vavai/riv/projekt of	Principles of Electrochemistry. Preparation of TiO2 (Anatase) Films on Electrodes by Anodic Oxidative Hydrolysis of TiCl3. Photooxidative Processes at the n-TiO 2 Surface. In situ FTIR Study of Anodic Photorections at the n-TiO 2 (Anatase) Electrode in Aprotic Electrolyte Solutions. Influence of X and R on the Emission of [Ru(X)(R)(CO) 2 (.alfa.-diimine)] (X=Halide, Mn(CO) 5 ; R=alkyl): Change of Character of the Lowest Excited State from MLCT (X=Cl) to XLCT (X=I) and .sigma..pi.* (X=Mn(CO) 5 ). Bond Activation by MLCT Excitation of Organometallic Compounds: Prompt CO-Photodissociation from [Cr(CO] 4 bpy]. A Spectroelectrochemical Study of Chemisorption, Anodic Polymerization and Degradation of Salicylic Acid on Conductor and TiO 2 Surfaces. Nanocrystalline TiO 2 (Anatase) Electrodes: Surface Morphology Adsorption, and Electrochemical Properties. Mechanism of an Alkyl-Dependent Photochemical Homolysis of the Re-Alkyl Bond in [Re(R)(CO) 3 (.alfa.-diimine)] Complexes via a Reactive .sigma..pi.* Excited State. Quantum Size Effects in Nanocrystalline Semiconducting Ti O2 Layers Prepared by Anodic Oxidative Hydrolysis of Ti Cl3. Design of a Temperature Microsensor with a Fast Response for Measurements in Living Cells. Anodic Oxidation of Acetonitrile Based Electrolyte Solutions. An in situ FTIR Study. Metal to Ligand Charge-Transfer Photochemistry of Metal-Metal-Bonded Complexes. 12. The Primary Photoprocess of (CO) 5 ReMn(CO) 3 (.alfa.-diimine) Complexes Studies by Temperature- and Pressur-Dependent Photochemistry and Pico- and Nanosecond Flash Photo Metal and Ligand Oxidation States in Dioxolene Complexes: Meaning, Assignment and Control. In-Situ FTIR Study of Anodic Photoreactions at the n-TiO 2 (anatase) Electrode in Aprotic Electrolyte Solutions. N/A First Direct Structural Information on a Reactive .sigma..pi.* Excited State: Time-Resolved UV-VIS and IR Spectroscopic Study of Re(Benzyl)(CO) 3 (iPr-DAB). Photochemistry and Emission of the Dinuclear Complexes (CO) 5 MnRe(CO) 3 (L) (L=2,2'-Bipyrimidine, 2,3-Bis-(2-pyridyl)pyrazine) and Bridged Trinuclear Complexes (CO) 5 MnRe(CO) 3 (L)Re(Br)CO) 3 and (CO) 5 MnRe(CO) 3 (BPYM)W(CO) 4 .Effect of the Remote M Polarography and Voltammetry of Mixed Titanium(IV) Oxide/Iron(III) Oxide Colloids. Polarography and Voltammetry of Aqueous Colloidal TiO 2 Solutions. Polarography and Voltammetry of Aqueous Colloidal SnO 2 Solutions. Polarography and Voltammetry of Ultrasmall Colloids: Introduction to a New Field. Bonding Properties of the 1,2-Semiquinone Radical-Anionic Ligand in the [M(CO) 4-n (L) n (DBSQ)] Complexes (M=Re, Mn; DBSQ = 3,5-di-tert-butyl-1,2-benzosemiquinone; n= O,1,2. A Comprehensive Spectroscopic (UV-Vis and IR Absorption, Resonance Raman, EPR) Character and Picosecond Dynamics of the Excited States of [Re(Br)(CO) 3 (.alfa.-diimine)] Complexes as a Function of the .alfa.-diimine Ligand: 4,4'-di-methyl-2,2'-bipyridine, N,N-di-p-tolyl-1,4-diaza-butadiene, and N,N-di-p-anisyl-1,4-diaza-butadiene. Anodic Oxidation of Dimethyl Sulfoxide Based Electrolyte Solutions. An in situ FTIR Study. Electrolysis at a Disc Electrode in a Thin Electrolyte Layer. Synthesis and Characterization of New Dinuclear Complexes (CO) 5 MnRe(CO) 3 (L) (L=2,2'-Bipyrimidine or 2,3-Bis-(2-pyridyl)pyrazine) and Trinuclear Compounds (CO) 5 MnRe(CO) 3 (L)R Complexes (R=Re(Br)(CO) 3 ,W(CO) 4 ). Study of Nanocrystalline Anatase Electrode in the Accumulation Regime. Excitation-Energy Dependent Photochemistry and Resonance Raman Spectra of Cr(CNPh) 6 . Halide-Dependent Change of the Lowest-Excited-State Character from MLCT to XLCT for the Complexes Re(X)(CO) 3 (.alfa.-diimine) (X=Cl, Br, I; .alfa.-diimine=bpy, iPr-PyCa, iPr-DAB) Studies by Resonance Raman, Time-Resolved Absorption and Emission Spectro Polarography and Voltammetry of Ultrasmall Colloids.
is http://linked.open...vavai/cep/projekt of	http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F93%2F0250/1994/ico%3A61388955 http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F93%2F0250/1994/orjk%3A11310 http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F93%2F0250/1995/ico%3A61388955 http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F93%2F0250/1995/orjk%3A11310 http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F93%2F0250/1996/ico%3A61388955 http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F93%2F0250/1996/orjk%3A11310

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