About: Mesoporous molecular sieves immobilized catalysts for olefin metathesis and related polymerizations

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rdf:type	http://linked.opendata.cz/ontology/domain/vavai/Projekt
rdfs:seeAlso	http://www.isvav.cz/projectDetail.do?rowId=GA203/02/0976
Description	The aim of the proposal is to develop new, reusable, highly active and selective heterogeneous catalysts for olefin metathesis, ring closing metathesis, ring opening metathesis polymerization and alkyne polymerization via immobilization of a series of homogeneous catalysts based on chlorides, oxychlorides and organometallic complexes of Mo, Rh and Ru on mesoporous molecular sieves. Special attention will be paid to the immobilization of well-defined metathesis catalysts (alkylidene complexes of Mo andRu). Metal species are to be attached to the support either directly via reaction with molecular sieves silanol groups or indirectly through organic spacers. The immobilized catalysts will be characterized using spectroscopic methods (NMR, IR, UV-VIS) and tested in reactions with model substrates (selected 1-alkenes, (-,(-dienes, cycloalkenes, monosubstituted acetylenes). The catalytic activity and selectivity of immobilized catalysts and their non-immobilized counterparts will be compared. The effect (en) Cílem projektu je vývoj nových, opakovaně použitelných, vysoce aktivních a selektivních heterogenních katalyzátorů metathesí olefinů (včetně metathesí s uzavřením kruhu), metathetických polymerizací cykloolefinů a polymerizací acetylenů cestou zakotvení série homogenních katalyzátorů typu chloridů, oxychloridů a organometalických komplexů molybdenu, rhodia a ruthenia na nosiči tvořeném mesoporézními molekulovými síty. Zvláštní pozornost bude věnována zakotvení dobře definovaných katalyzátorů metathesí -alkylidenových komplexů molybdenu a ruthenia. Homogenní katalyzátory budou zakotveny na nosiči buď přímo jejich reakcí se silanolovými hydroxyly nebo nepřímo pomocí vhodně funkcionalizovaných organických molekul (%22spacerů%22). Zakotvené katalyzátory budou charakterizovány pomocí spektroskopických metod (NMR, IR, UV-VIS) a jejich aktivita a selektivita budou testovány v reakcích s modelovými substráty (vybrané 1-alkeny, (-,(-dieny, cykloalkeny, monosubstituované acetyleny). Získané výsledky budou porovnány
Title	Mesoporous molecular sieves immobilized catalysts for olefin metathesis and related polymerizations (en) Katalyzátory metathesí olefinů a příbuzných polymerizací zakotvené na mesoporézních molekulových sítech
skos:notation	GA203/02/0976
http://linked.open...avai/cep/aktivita	Standard projects
http://linked.open...kovaStatniPodpora	http://linked.opendata.cz/resource/domain/vavai/projekt/GA203%2F02%2F0976/celkovaStatniPodpora
http://linked.open...ep/celkoveNaklady	http://linked.opendata.cz/resource/domain/vavai/projekt/GA203%2F02%2F0976/celkoveNaklady
http://linked.open...datumDodatniDoRIV	2008-06-02 (xsd:date)
http://linked.open...i/cep/druhSouteze	VS - Veřejná soutěž ve výzkumu a vývoji
http://linked.open...ep/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open.../cep/fazeProjektu	1564656
http://linked.open...ai/cep/hlavniObor	CF - Fyzikální chemie a teoretická chemie
http://linked.open...hodnoceniProjektu	U - Uspěl podle zadání, tj. byly splněny cíle a jeho předpokládané výsledky uvedené ve smlouvě / rozhodnutí o poskytnutí podpory
http://linked.open...vai/cep/kategorie	ZV - Základní výzkum
http://linked.open.../cep/klicovaSlova	Neuvedeno. (en)
http://linked.open...ep/partnetrHlavni	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...inujicichPrijemcu	0 (xsd:int)
http://linked.open...cep/pocetPrijemcu	1 (xsd:int)
http://linked.open...ocetSpoluPrijemcu	1 (xsd:int)
http://linked.open.../pocetVysledkuRIV	36 (xsd:int)
http://linked.open...enychVysledkuVRIV	36 (xsd:int)
http://linked.open...okUkonceniPodpory	2004
http://linked.open...okZahajeniPodpory	2002
http://linked.open...iciPoslednihoRoku	2005
http://linked.open...atUdajeProjZameru	2005
http://linked.open.../vavai/cep/soutez	SGA02002GA-ST
http://linked.open...usZobrazovaneFaze	DUU
http://linked.open...ai/cep/typPojektu	P - Projekt výzkumu a vývoje financovaný ze státního rozpočtu
http://linked.open.../cep/vedlejsiObor	CD - Makromolekulární chemie CA - Anorganická chemie
http://linked.open...jektu+dodavatelem	New highly active and selective catalysts for olefin metathesis and related polymerizations were prepared using mesoporous molecular sieves. (1) New hybrid catalysts for polymerization of substituted acetylenes were prepared by anchoring neutral Rh(diene (en) V průběhu řešení byly připraveny nové vysoce aktivní a selektivní katalyzátory metathese olefinů a příbuzných polymerizací využívající mesoporézní molekulová síta jako nosiče. (1) Nové hybridní katalyzátory pro polymerizace substituovaných acetylenů byly (cs)
http://linked.open...tniCyklusProjektu	ZBKU
is http://linked.open...vavai/riv/projekt of	Controlled and Living Polymerizations Induced with Rhodium-based Catalysts Homogenous and Hybrid Catalysts for Phenylacetylene Polymerization Formed by Ligand Exchange Activation of Rh Complexes with Cyclooctatetraene. Hybrid Catalysts Prepared by Anchoring Rh-complexes on Mesoporous Molecular Sieves and their Activity in Polymerization of Substituted Acetylenes Homogenous and Hybrid Catalysts for Phenylacetylene Polymerization Formed by Ligand Exchange Activation of Rh-comlexes with Cyclooctatetraene. MCM-41 Anchored Schrock Catalysts Mo(=CHCMe2Ph)(=N-2,6-i-Pr2C6H3)(OCMe(CF3)2)2 - Activity in 1 - heptene metathesis and cometathesis. Preparation of Hybrid Catalysts by anchoring Rh-complexes on Mesoporous Molecular Sieves and their Activity in Polymerization of Substituted Acetylenes. Controlled and Living Polymerizations Induced with Rhodium Catalysts. A Review Co-ordination Polymerization of Phenylacetylen and Atom Transfer Radical Polymerization of Vinyl Monomers Induced by Oxalamidinato Rh-Complexes Controlled Polymerizations Induced with Rhodium Catalysts MCM-41 Anchored Schrock Catalyst Mo(=CHCMe2Ph)(=N-2,6-i-Pr2C6H3)(OCMe(CF3)2)2 -Activity in 1-Heptene Metathesis and Cross-metathesis Reactions. Activity of Rh(cycloocta-1,5-diene) complexes in ATRP of styrene and methacrylates Degradace autooxidací a cis-trans izomerizace substituovaných polyfenylacetylenů Mesoporous Molecular Sieves Immobilized catalysts for Polymerization of Phenylacetylene and its Derivatives Mesoporous molecular sieves immobilized catalysts for polymerization of phenylacetylenes and its derivatives Nové Rh(dienové) komplexy a jejich aktivita při polymerizaci fenylacetylenů Rh(diene) complexes anchored on polybenzimidazole and MCM-41 mesoporous supports: heterophase catalysts for polymerization of substituted acetylenes Diene Complexes of Rh and Ir anchored on polybenzimidazole Mutual interconnection of the cis-to-trans izomerization and autooxidative degradation of substituted polyvinylenes Mesoporous Molecular Sieves MCM-41 Supported MoCl5-catalyst for Alkene Metathesis and Metathesis Polymerization Mesoporous Molecular Sieves Immobilized Catalysts for Polymerization of Phenylacetylene and its Derivatives Mesoporous Molecular Sieves Immobilized Catalysts for Polymerization of Phenylacetylene and its Derivatives. Polymerization of Substited Acetylenes With Rh(diene)(acac) Complexes Polymerization of Substitured Acetylenes with [Rh(diene)(acac)] Complexes Polymerization of Phenylacetylene with [Rh(cod)Cl]2 Complex Anchored on Inorganic and Organic Supports Polymerizations Catalyzed with Rhodium Complexes Polymerization of Substitured Acetylenes with [Rh(diene)(acac)] Complexes Polymerizations Catalyzed with Rhodium Complexes. [Rh(cod)Cl]2 complex anchored on mesoporous molecular sieves: hybrid polymerization catalysts [Rh(cod)Cl]2 Complex Immobilised on Mesoporous Molecular Sieves MCM-41 - a New Hybrid Catalyst for Polymerization of Phenylacetylene [Rh(cod)Cl]2 Complex Immobilized on Mesoporous Molecular Sieves MCM-41 ů A New Hybrid Catalyst for Polymerization of Phenylacetylene. Hybrid Catalysts for Acetylenes Polymerization Prepared by Anchoring [Rh(cod)Cl]2 on MCM-41, MCM-48 and SBA-15 Mesoporous Molecular Sieves - the Effect of Support Structure on Catalytic Activity in Polymerization od Phenylacetylene and 4-Ethynyl-N- Hybrid Catalysts for Acetylenes Polymerization Prepared by Anchoring [Rh(cod)Cl]2 Complex on MCM-41, MCM-48 and SBA-15 Mesoporous Molecular Sieves Hybrid Polymerization Catalysts Prepared by Anchoring Rh(diene) Complexes on MCM-41, MCM-48 and SBA-15 Mesoporous Molecular Sieves Hybrid Catalysts for Acetylenes Polymerization Prepared by Anchoring [Rh(cod)Cl]2 on MCM-41, MCM-48 and SBA-15 Mesoporous Molecular Sieves - The Effect of Support Structure on Catalytic Activity in Polymerization of Phenylacetylene and 4-ethynal- N-(4-[t Synthesis of Rh Carboxylate and Phosphine Complexes and their Activity in Polymerization of Substituted Acetylenes Rhenium Oxide Supported on Mesoporous Organized Alumina as a Catalyst for Metathesis of 1-alkenes
is http://linked.open...vavai/cep/projekt of	http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F02%2F0976/2002/ico%3A61388955 http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F02%2F0976/2002/orjk%3A11310 http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F02%2F0976/2003/ico%3A61388955 http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F02%2F0976/2003/orjk%3A11310 http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F02%2F0976/2004/ico%3A61388955 http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F02%2F0976/2004/orjk%3A11310 http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F02%2F0976/2005/ico%3A61388955 http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F02%2F0976/2005/orjk%3A11310 http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F02%2F0976/2007/ico%3A61388955 http://linked.opendata.cz/resource/domain/vavai/cep/ucast/GA203%2F02%2F0976/2007/orjk%3A11310

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