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Description
| - This work deals with the synthesis and chemical-physical characterization of a new series of liquid crystalline elastomers (LCEs) in the form of monodomain films, showing the nematic and smectic A phases. The synthesis, mesomorphic characterization and 2H NMR study of two constituent mesogens is reported, as well as the preparation of monodomain and polydomain polysiloxane-based side-chain LC elastomers containing different concentrations of the two mesogens and a constant crosslinking density of 15%. The phase diagram and mesomorphic behaviour of these new liquid crystalline elastomers were determined by DSC, POM and X-ray diffraction studies. Thermo-mechanic curves confirmed the shape-memory properties of these films, which have elastic properties optimal for applications as thermo-mechanic actuators.
- This work deals with the synthesis and chemical-physical characterization of a new series of liquid crystalline elastomers (LCEs) in the form of monodomain films, showing the nematic and smectic A phases. The synthesis, mesomorphic characterization and 2H NMR study of two constituent mesogens is reported, as well as the preparation of monodomain and polydomain polysiloxane-based side-chain LC elastomers containing different concentrations of the two mesogens and a constant crosslinking density of 15%. The phase diagram and mesomorphic behaviour of these new liquid crystalline elastomers were determined by DSC, POM and X-ray diffraction studies. Thermo-mechanic curves confirmed the shape-memory properties of these films, which have elastic properties optimal for applications as thermo-mechanic actuators. (en)
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Title
| - Effect of co-monomers’ relative concentration on self-assembling behaviour of side-chain liquid crystalline elastomers
- Effect of co-monomers’ relative concentration on self-assembling behaviour of side-chain liquid crystalline elastomers (en)
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skos:prefLabel
| - Effect of co-monomers’ relative concentration on self-assembling behaviour of side-chain liquid crystalline elastomers
- Effect of co-monomers’ relative concentration on self-assembling behaviour of side-chain liquid crystalline elastomers (en)
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skos:notation
| - RIV/68378271:_____/14:00434554!RIV15-GA0-68378271
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/68378271:_____/14:00434554
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - liquid crystal elastomers; nematic; smectic A; NMR; X-ray diffraction; DSC; thermo-mechanic properties; elastic properties; phase diagram (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Bubnov, Alexej
- Gorecka, E.
- Hamplová, Věra
- Pociecha, D.
- Domenici, V.
- Zalar, B.
- Zupančič, B.
- Milavec, J.
- Rešetič, A.
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
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