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  • A thin (3-aminopropyl)triethoxysilane (3APTS) layer with a grafting density around 50 groups per nm2 was coated onto soft magnetic carbonyl iron (CI) particles. Their physical characteristics were examined using various methods, and the results revealed that the coating layer did not affect the particles' morphology and magnetic properties while their resistance against thermal oxidation and chemical degradation was considerably improved. This study further evaluates the surface free energy of the particles under investigation using tensiometry, namely capillary rise experimental methods based on the Washburn theory. The dispersive and polar components of surface free energy were subsequently computed through the application of the Owens–Wendt–Rabel–Kaeble theory. It was observed that the coating of CI particles with 3APTS increased the dispersive component of surface free energy, resulting in the improved compatibility of such particles with non-polar silicone oil which is used as a carrier liquid for magnetorheological (MR) suspensions. Furthermore, the 3APTS coating has a negligible influence on MR properties in comparison with an uncoated CI particle-based MR suspension, as was proved by steady shear and small-strain oscillatory shear tests under various external magnetic fields. The improved compatibility of 3APTS-coated CI particles with silicone oil was reflected in the better sedimentation stability of the MR suspension, observed via tensiometry for the first time for MR suspensions, in comparison with the uncoated CI particle-based suspension.
  • A thin (3-aminopropyl)triethoxysilane (3APTS) layer with a grafting density around 50 groups per nm2 was coated onto soft magnetic carbonyl iron (CI) particles. Their physical characteristics were examined using various methods, and the results revealed that the coating layer did not affect the particles' morphology and magnetic properties while their resistance against thermal oxidation and chemical degradation was considerably improved. This study further evaluates the surface free energy of the particles under investigation using tensiometry, namely capillary rise experimental methods based on the Washburn theory. The dispersive and polar components of surface free energy were subsequently computed through the application of the Owens–Wendt–Rabel–Kaeble theory. It was observed that the coating of CI particles with 3APTS increased the dispersive component of surface free energy, resulting in the improved compatibility of such particles with non-polar silicone oil which is used as a carrier liquid for magnetorheological (MR) suspensions. Furthermore, the 3APTS coating has a negligible influence on MR properties in comparison with an uncoated CI particle-based MR suspension, as was proved by steady shear and small-strain oscillatory shear tests under various external magnetic fields. The improved compatibility of 3APTS-coated CI particles with silicone oil was reflected in the better sedimentation stability of the MR suspension, observed via tensiometry for the first time for MR suspensions, in comparison with the uncoated CI particle-based suspension. (en)
Title
  • A tensiometric study of magnetorheological suspensions' stability
  • A tensiometric study of magnetorheological suspensions' stability (en)
skos:prefLabel
  • A tensiometric study of magnetorheological suspensions' stability
  • A tensiometric study of magnetorheological suspensions' stability (en)
skos:notation
  • RIV/70883521:28610/14:43871926!RIV15-MSM-28610___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ED2.1.00/03.0111), P(GP14-32114P)
http://linked.open...iv/cisloPeriodika
  • 102
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 1239
http://linked.open...ai/riv/idVysledku
  • RIV/70883521:28610/14:43871926
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Stability; Tensiometry; Powder wetting; Core-shell; Capillary rise; Magnetorheology (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [FE4590419A78]
http://linked.open...i/riv/nazevZdroje
  • RSC Advances: an international journal to further the chemical sciences
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 4
http://linked.open...iv/tvurceVysledku
  • Pavlínek, Vladimír
  • Sedlačík, Michal
http://linked.open...ain/vavai/riv/wos
  • 000345460800037
issn
  • 2046-2069
number of pages
http://bibframe.org/vocab/doi
  • 10.1039/c4ra11842a
http://localhost/t...ganizacniJednotka
  • 28610
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