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  • The effect of photodegradation in isotactic poly(1-butene) (PB-1) have been investigated using rheology, differential scanning calorimetry and infrared spectroscopy. Two commercially available grades of PB-1 with different average molecular weight were chosen. Specimens prepared by compression moulding were UV irradiated in the interval from 0 to 70 h. UV-induced changes in molecular structure have been followed by evolution of rheological properties, thermal properties and degradation by-products. Thermal analysis showed significant changes in crystallization behaviour influencing morphology and resulting thermal properties. Moreover it has been confirmed that the degradation significantly retards the phase transformation. Rheological measurement has been found as an effective method for determination of early stages of photodegradation of PB-1.
  • The effect of photodegradation in isotactic poly(1-butene) (PB-1) have been investigated using rheology, differential scanning calorimetry and infrared spectroscopy. Two commercially available grades of PB-1 with different average molecular weight were chosen. Specimens prepared by compression moulding were UV irradiated in the interval from 0 to 70 h. UV-induced changes in molecular structure have been followed by evolution of rheological properties, thermal properties and degradation by-products. Thermal analysis showed significant changes in crystallization behaviour influencing morphology and resulting thermal properties. Moreover it has been confirmed that the degradation significantly retards the phase transformation. Rheological measurement has been found as an effective method for determination of early stages of photodegradation of PB-1. (en)
Title
  • Photodegradation of isotactic poly(1-butene): Multiscale characterization
  • Photodegradation of isotactic poly(1-butene): Multiscale characterization (en)
skos:prefLabel
  • Photodegradation of isotactic poly(1-butene): Multiscale characterization
  • Photodegradation of isotactic poly(1-butene): Multiscale characterization (en)
skos:notation
  • RIV/70883521:28610/11:43865627!RIV12-MSM-28610___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ED2.1.00/03.0111), Z(MSM7088352101)
http://linked.open...iv/cisloPeriodika
  • 10
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 220241
http://linked.open...ai/riv/idVysledku
  • RIV/70883521:28610/11:43865627
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Infrared spectroscopy||Isotactic poly(1-butene)||Photodegradation||Rheology||Thermal behaviour (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [054C221F17B5]
http://linked.open...i/riv/nazevZdroje
  • Polymer Degradation and Stability
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 96
http://linked.open...iv/tvurceVysledku
  • Commereuc, Sophie
  • Verney, Vincent
  • Čermák, Roman
  • Obadal, Martin
  • Beníček, Lubomír
  • Chvátalová, Lenka
http://linked.open...ain/vavai/riv/wos
  • 000295501000005
http://linked.open...n/vavai/riv/zamer
issn
  • 0141-3910
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.polymdegradstab.2011.08.001
http://localhost/t...ganizacniJednotka
  • 28610
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