About: Orientation of HDPE inclusions within solid-state drawn rubber-modified isotactic polypropylene: DSC insight     Goto   Sponge   NotDistinct   Permalink

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Description
  • Effect of drawing temperature on the melting behavior of oriented isotactic polypropylene (PP) modified with ethylene-propylene-diene monomer rubber with a small amount of high-density polyethylene (HDPE) is explored in this study. Injection-molded specimens both neat and 8 vol % modified PP were solid-state drawn to natural drawing ratio and characterized by X-ray diffraction, dynamic mechanical analysis (DMA), Charpy impact test and differential scanning calorimetry (DSC). A synergy of orientation and embedding rubber particles caused a significant increase of low-temperature notched impact strength of oriented blends. It was shown, that the DSC method can be used successfully for the indirect but very sensitive characterization of orientation on a nanometre scale. At the drawing temperature of 120°C, the DSC data indicated an incomplete transition of the PP crystalline structure: This is reflected by splitting and shifting of the melting peak of PP. An increase of the melting temperature of the HDPE inclusions by 3.5°C reflects the high orientation.
  • Effect of drawing temperature on the melting behavior of oriented isotactic polypropylene (PP) modified with ethylene-propylene-diene monomer rubber with a small amount of high-density polyethylene (HDPE) is explored in this study. Injection-molded specimens both neat and 8 vol % modified PP were solid-state drawn to natural drawing ratio and characterized by X-ray diffraction, dynamic mechanical analysis (DMA), Charpy impact test and differential scanning calorimetry (DSC). A synergy of orientation and embedding rubber particles caused a significant increase of low-temperature notched impact strength of oriented blends. It was shown, that the DSC method can be used successfully for the indirect but very sensitive characterization of orientation on a nanometre scale. At the drawing temperature of 120°C, the DSC data indicated an incomplete transition of the PP crystalline structure: This is reflected by splitting and shifting of the melting peak of PP. An increase of the melting temperature of the HDPE inclusions by 3.5°C reflects the high orientation. (en)
Title
  • Orientation of HDPE inclusions within solid-state drawn rubber-modified isotactic polypropylene: DSC insight
  • Orientation of HDPE inclusions within solid-state drawn rubber-modified isotactic polypropylene: DSC insight (en)
skos:prefLabel
  • Orientation of HDPE inclusions within solid-state drawn rubber-modified isotactic polypropylene: DSC insight
  • Orientation of HDPE inclusions within solid-state drawn rubber-modified isotactic polypropylene: DSC insight (en)
skos:notation
  • RIV/70883521:28110/13:43869808!RIV14-MSM-28110___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, V
http://linked.open...iv/cisloPeriodika
  • 1
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http://linked.open...aciTvurceVysledku
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  • 94634
http://linked.open...ai/riv/idVysledku
  • RIV/70883521:28110/13:43869808
http://linked.open...riv/jazykVysledku
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  • blends, differential scanning calorimetry, orientation, polyolefins, structure-property relations (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [413EE6C97C81]
http://linked.open...i/riv/nazevZdroje
  • Journal of Applied Polymer Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 130
http://linked.open...iv/tvurceVysledku
  • Raab, Miroslav
  • Sližová, Marta
http://linked.open...ain/vavai/riv/wos
  • 000321305500072
issn
  • 0021-8995
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/app.39207
http://localhost/t...ganizacniJednotka
  • 28110
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