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  • Nanofibrous membranes were prepared from the poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) solution by electrospinning technique. PPO membranes with the mean fiber diameter of 150 nm exhibited high porosity (80%) and suitable transport properties. Four nanofiber catalysts with different platinum contents ranging from 1.4 to 2.7 wt.% were prepared by the membrane wet impregnation with the solution of platinum(II) acetylacetonate and subsequent activation by calcination in air at 175 degrees C. The catalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and chemical analysis (ICP-MS). The catalytic activity of Pt nanoparticles supported on electrospun membranes was tested in total oxidation of ethanol in air as a model reaction. The catalysts with platinum loading from 1.4 to 2.7 wt.% achieved 50% conversion of ethanol between 163 and 202 degrees C.
  • Nanofibrous membranes were prepared from the poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) solution by electrospinning technique. PPO membranes with the mean fiber diameter of 150 nm exhibited high porosity (80%) and suitable transport properties. Four nanofiber catalysts with different platinum contents ranging from 1.4 to 2.7 wt.% were prepared by the membrane wet impregnation with the solution of platinum(II) acetylacetonate and subsequent activation by calcination in air at 175 degrees C. The catalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and chemical analysis (ICP-MS). The catalytic activity of Pt nanoparticles supported on electrospun membranes was tested in total oxidation of ethanol in air as a model reaction. The catalysts with platinum loading from 1.4 to 2.7 wt.% achieved 50% conversion of ethanol between 163 and 202 degrees C. (en)
Title
  • Preparation and characterization of electrospun poly(p-phenylene oxide) membranes
  • Preparation and characterization of electrospun poly(p-phenylene oxide) membranes (en)
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  • Preparation and characterization of electrospun poly(p-phenylene oxide) membranes
  • Preparation and characterization of electrospun poly(p-phenylene oxide) membranes (en)
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  • RIV/70883521:28110/12:43868008!RIV13-MSM-28110___
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  • I, P(GAP204/11/1206), P(GPP106/11/P459), V
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  • 1
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  • 161314
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  • RIV/70883521:28110/12:43868008
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  • Volatile organic compounds; Oxidation; Nanofibrous membrane; Poly(2,6-dimethyl-1,4-phenylene oxide); Electrospinning (en)
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  • NL - Nizozemsko
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  • [05FA44CD2904]
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  • Catalysis Today
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  • 193
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  • Slobodian, Petr
  • Topka, Pavel
  • Šolcová, Olga
  • Petráš, David
  • Soukup, Karel
http://linked.open...ain/vavai/riv/wos
  • 000308675900024
issn
  • 0920-5861
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.cattod.2012.03.019
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  • 28110
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