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  • This paper is focused on the chemical and morphology changes in the surface of poly(1-butene) (PB-1) generated by plasma treatment. The radio frequency capacitively coupled plasma (air, argon, argon then allylamine, argon containing ammonia and argon with octafluorocyclobutane) was used. Modified surface of PB-1 was characterized by contact angle measurements, X-ray photoelectron spectroscopy, and atomic force microscopy. The surface hydrophilization by air and argon with ammonia plasmas was evaluated as most sufficient. Oppositely, a high level of hydrophobicity of PB-1 surface was reached by combination of argon with octafluorocyclobutane plasma. Upon plasma modification, hydrophilicity/ hydrophobicity of treated surfaces remained stable within three days under air atmosphere and then values of contact angle slowly recovered to those of unmodified PB-1. However, morphology and surface chemical composition of plasma-modified samples remained generally unchanged during observed time. Changes in surface hydrophilicity/hydrophobicity of plasma-treated PB-1 were attributed to variance of conformation of the surface molecules.
  • This paper is focused on the chemical and morphology changes in the surface of poly(1-butene) (PB-1) generated by plasma treatment. The radio frequency capacitively coupled plasma (air, argon, argon then allylamine, argon containing ammonia and argon with octafluorocyclobutane) was used. Modified surface of PB-1 was characterized by contact angle measurements, X-ray photoelectron spectroscopy, and atomic force microscopy. The surface hydrophilization by air and argon with ammonia plasmas was evaluated as most sufficient. Oppositely, a high level of hydrophobicity of PB-1 surface was reached by combination of argon with octafluorocyclobutane plasma. Upon plasma modification, hydrophilicity/ hydrophobicity of treated surfaces remained stable within three days under air atmosphere and then values of contact angle slowly recovered to those of unmodified PB-1. However, morphology and surface chemical composition of plasma-modified samples remained generally unchanged during observed time. Changes in surface hydrophilicity/hydrophobicity of plasma-treated PB-1 were attributed to variance of conformation of the surface molecules. (en)
Title
  • The effect of plasma treatment on structure and properties of poly(1-butene) surface
  • The effect of plasma treatment on structure and properties of poly(1-butene) surface (en)
skos:prefLabel
  • The effect of plasma treatment on structure and properties of poly(1-butene) surface
  • The effect of plasma treatment on structure and properties of poly(1-butene) surface (en)
skos:notation
  • RIV/70883521:28110/12:43867489!RIV13-MSM-28110___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ED2.1.00/03.0111), P(GD104/09/H080), S, Z(MSM7088352101)
http://linked.open...iv/cisloPeriodika
  • 4
http://linked.open...vai/riv/dodaniDat
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  • 133198
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  • RIV/70883521:28110/12:43867489
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  • Isotactic poly(1-butene), Plasma treatment Surface modification, XPS, AFM (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [1689E0A2F99F]
http://linked.open...i/riv/nazevZdroje
  • European Polymer Journal
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 48
http://linked.open...iv/tvurceVysledku
  • Ponížil, Petr
  • Sajdl, Petr
  • Vesel, Alenka
  • Cvelbar, Uroš
  • Čermák, Roman
  • Minařík, Antonín
  • Mráček, Aleš
  • Beníček, Lubomír
  • Chvátalová, Lenka
  • Grulich, Ondřej
http://linked.open...ain/vavai/riv/wos
  • 000302846700023
http://linked.open...n/vavai/riv/zamer
issn
  • 0014-3057
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.eurpolymj.2012.02.007
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  • 28110
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