About: Preparation and characterization of an epoxy resin modified by a combination of MDI-based polyurethane and montmorillonite     Goto   Sponge   NotDistinct   Permalink

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Description
  • The present work investigates the modification of epoxy resin by using a combination of nanoclay (montmorillonite-Cloisite 30B) and a liquid polymeric modifier (polyurethane). Polyurethane was obtained from 4,4´- diphenylmethane diisocyanate and polydiols with different molecular weight: polyethylene glycol (PEG 400) and polyoxypropylene diols with molecular weight 1000 g/mol and 2000 g/mol. The impact strength, the critical stress intensity factor as well as the flexural strength were evaluated as functions of modifiers content. The obtained results showed that hybrid composites exhibit enhanced mechanical properties without significant changes of the glass transition temperature. FTIR analysis showed that chemical reactions took place between the hydroxyl groups of epoxy resin and the isocyanate groups of polyurethane, explaining an improvement of the mechanical properties of epoxy resin. However, XRD results demonstrated the formation of an exfoliated structure for the hybrid compositions with both polyurethane and montmorillonite.
  • The present work investigates the modification of epoxy resin by using a combination of nanoclay (montmorillonite-Cloisite 30B) and a liquid polymeric modifier (polyurethane). Polyurethane was obtained from 4,4´- diphenylmethane diisocyanate and polydiols with different molecular weight: polyethylene glycol (PEG 400) and polyoxypropylene diols with molecular weight 1000 g/mol and 2000 g/mol. The impact strength, the critical stress intensity factor as well as the flexural strength were evaluated as functions of modifiers content. The obtained results showed that hybrid composites exhibit enhanced mechanical properties without significant changes of the glass transition temperature. FTIR analysis showed that chemical reactions took place between the hydroxyl groups of epoxy resin and the isocyanate groups of polyurethane, explaining an improvement of the mechanical properties of epoxy resin. However, XRD results demonstrated the formation of an exfoliated structure for the hybrid compositions with both polyurethane and montmorillonite. (en)
Title
  • Preparation and characterization of an epoxy resin modified by a combination of MDI-based polyurethane and montmorillonite
  • Preparation and characterization of an epoxy resin modified by a combination of MDI-based polyurethane and montmorillonite (en)
skos:prefLabel
  • Preparation and characterization of an epoxy resin modified by a combination of MDI-based polyurethane and montmorillonite
  • Preparation and characterization of an epoxy resin modified by a combination of MDI-based polyurethane and montmorillonite (en)
skos:notation
  • RIV/70883521:28110/11:43865736!RIV12-MSM-28110___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM7088352101)
http://linked.open...iv/cisloPeriodika
  • 5
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 223031
http://linked.open...ai/riv/idVysledku
  • RIV/70883521:28110/11:43865736
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • polyurethane; nanocomposites; montmorillonite; mechanical properties; MDI; epoxy resin (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [942BFDBC057D]
http://linked.open...i/riv/nazevZdroje
  • Journal of Applied Polymer Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 122
http://linked.open...iv/tvurceVysledku
  • Hausnerová, Berenika
  • Kostrzewa, Marcin
  • Bakar, Mohamed Abu
  • Pajak,, Karolina
http://linked.open...ain/vavai/riv/wos
  • 000295538600045
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-8995
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/app.34347
http://localhost/t...ganizacniJednotka
  • 28110
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