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  • TiO2 hollow microspheres with sea urchin-like hierarchical architectures were synthesized by a simple hydrothermal method. The as-synthesized hollow microspheres with hierarchical architectures consisting of many rhombic building units exhibit high specific surface area. Electrorheological (ER) properties of hierarchical hollow TiO2-based suspension were investigated under steady and oscillatory shear. The hollow TiO2-based suspensions show much higher yield stress and elasticity than pure TiO2 suspension at the same electric field strength. This phenomenon was elucidated well in view of their dielectric spectra analysis. The sea urchin-like architectures result in stronger interfacial polarization of hollow TiO2 suspension upon an electric field, showing higher ER activity. Also, hollow interiors of TiO2 particles increase the long-term stability of suspensions and further merit the ER effect.
  • TiO2 hollow microspheres with sea urchin-like hierarchical architectures were synthesized by a simple hydrothermal method. The as-synthesized hollow microspheres with hierarchical architectures consisting of many rhombic building units exhibit high specific surface area. Electrorheological (ER) properties of hierarchical hollow TiO2-based suspension were investigated under steady and oscillatory shear. The hollow TiO2-based suspensions show much higher yield stress and elasticity than pure TiO2 suspension at the same electric field strength. This phenomenon was elucidated well in view of their dielectric spectra analysis. The sea urchin-like architectures result in stronger interfacial polarization of hollow TiO2 suspension upon an electric field, showing higher ER activity. Also, hollow interiors of TiO2 particles increase the long-term stability of suspensions and further merit the ER effect. (en)
Title
  • Synthesis and electrorheological characteristics of sea urchin-like TiO(2) hollow spheres
  • Synthesis and electrorheological characteristics of sea urchin-like TiO(2) hollow spheres (en)
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  • Synthesis and electrorheological characteristics of sea urchin-like TiO(2) hollow spheres
  • Synthesis and electrorheological characteristics of sea urchin-like TiO(2) hollow spheres (en)
skos:notation
  • RIV/70883521:28110/11:43865328!RIV12-MSM-28110___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA202/09/1626), Z(MSM7088352101)
http://linked.open...iv/cisloPeriodika
  • 7
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  • 233868
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  • RIV/70883521:28110/11:43865328
http://linked.open...riv/jazykVysledku
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  • Hollow TiO2 spheres – Sea urchin-like – Electrorheological fluid – Dielectric properties – Viscoelastic properties (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [5886A98DAB64]
http://linked.open...i/riv/nazevZdroje
  • Colloid & Polymer Science
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http://linked.open...ichTvurcuVysledku
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http://linked.open...v/svazekPeriodika
  • 287
http://linked.open...iv/tvurceVysledku
  • Pavlínek, Vladimír
  • Sáha, Petr
  • Cheng, Qilin
  • Li, Chunzhong
  • He, Ying
  • Yan, Yanfang
http://linked.open...ain/vavai/riv/wos
  • 000290538000007
http://linked.open...n/vavai/riv/zamer
issn
  • 0303-402X
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s00396-011-2398-8
http://localhost/t...ganizacniJednotka
  • 28110
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