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  • The paper deals with the effects of nucleation on photodegradation of isotactic polypropylene. The starting polymer was modified by a specific α-nucleating/clarifying agent Millad 3988 based on 1,3;2,4-bis(3,4- dimethylbenzylidene) sorbitol. Several concentrations were applied. Samples prepared by compression moulding were then exposed to UV-irradiation. Infrared spectroscopy showed that the degradation kinetics is similar for all the samples. Melting and crystallization behaviour of irradiated samples was followed using a differential scanning calorimetry. In all cases UV-irradiation led to decrease of melting/crystallization temperature as a result of polymer degradation. The surface cracking was observed using polarized light microscopy. The network of the surface cracking was significantly different for neat and nucleated samples.
  • The paper deals with the effects of nucleation on photodegradation of isotactic polypropylene. The starting polymer was modified by a specific α-nucleating/clarifying agent Millad 3988 based on 1,3;2,4-bis(3,4- dimethylbenzylidene) sorbitol. Several concentrations were applied. Samples prepared by compression moulding were then exposed to UV-irradiation. Infrared spectroscopy showed that the degradation kinetics is similar for all the samples. Melting and crystallization behaviour of irradiated samples was followed using a differential scanning calorimetry. In all cases UV-irradiation led to decrease of melting/crystallization temperature as a result of polymer degradation. The surface cracking was observed using polarized light microscopy. The network of the surface cracking was significantly different for neat and nucleated samples. (en)
Title
  • Photodegradation of Polypropylene with sorbitol-based nucleating agent
  • Photodegradation of Polypropylene with sorbitol-based nucleating agent (en)
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  • Photodegradation of Polypropylene with sorbitol-based nucleating agent
  • Photodegradation of Polypropylene with sorbitol-based nucleating agent (en)
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  • RIV/70883521:28110/10:63509304!RIV11-MSM-28110___
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  • I, Z(MSM7088352101)
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  • 278818
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  • RIV/70883521:28110/10:63509304
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  • polypropylene; nucleating agent; sorbitol; photodegradation; polymorphis (en)
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  • [2F0718D3C7BE]
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  • Navrátilová, Jana
  • Čermák, Roman
  • Vašek, Leoš
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  • WSEAS Press
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  • 978-960-474-203-5
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  • 28110
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