About: The First Entry to Pyrrolo[2,3-c]quinoline-2,4(3aH,5H)-diones

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Wittig olefination of 3-aminoquinoline-2,4(1H,3H)-diones with ethyl (triphenylphosphoranylidene)acetate afforded (E)-3-amino-4-ethoxycarbonylmethylene-1,2,3,4-tetrahydro-2-quinolones and pyrrolo[2,3-c]quinoline-2,4(3aH,5H)-diones. An alternative approach for the synthesis of pyrrolo[2,3-c]quinoline-2,4(3aH,5H)-diones via 3-bromoacetamidoquinoline-2,4(1H,3H)-diones, their corresponding triphenylphosphonium salts, and ylides that undergo intramolecular Wittig reaction, was investigated. Wittig olefination of 3-aminoquinoline-2,4(1H,3H)-diones with ethyl (triphenylphosphoranylidene)acetate afforded (E)-3-amino-4-ethoxycarbonylmethylene-1,2,3,4-tetrahydro-2-quinolones and pyrrolo[2,3-c]quinoline-2,4(3aH,5H)-diones. An alternative approach for the synthesis of pyrrolo[2,3-c]quinoline-2,4(3aH,5H)-diones via 3-bromoacetamidoquinoline-2,4(1H,3H)-diones, their corresponding triphenylphosphonium salts, and ylides that undergo intramolecular Wittig reaction, was investigated. (en) Wittigovou olefinací 3-aminochinoline-2,4(1H,3H)-dionů ethyl-(trifenylfosphoranylidene)acetátem byly připraveny (E)-3-amino-4-ethoxykarbonylmethylen-1,2,3,4-tetrahydro-2-chinolony a pyrrolo[2,3-c]chinolin-2,4(3aH,5H)-diony. Byla prozkoumána alternativní metoda syntézy pyrrolo[2,3-c]chinolin-2,4(3aH,5H)-dionů přes 3-bromacetamidochinolin-2,4(1H,3H)-diony, odpovídající trifenylfosphoniové soli a ylidy, které podléhají intramolekulární Wittigově reakci. (cs)
Title	The First Entry to Pyrrolo[2,3-c]quinoline-2,4(3aH,5H)-diones The First Entry to Pyrrolo[2,3-c]quinoline-2,4(3aH,5H)-diones (en) První přístup k pyrrolo[2,3-c]chinolin-2,4(3aH,5H)-dionům (cs)
skos:prefLabel	The First Entry to Pyrrolo[2,3-c]quinoline-2,4(3aH,5H)-diones The First Entry to Pyrrolo[2,3-c]quinoline-2,4(3aH,5H)-diones (en) První přístup k pyrrolo[2,3-c]chinolin-2,4(3aH,5H)-dionům (cs)
skos:notation	RIV/70883521:28110/08:63507052!RIV09-GA0-28110___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/07/0320), P(MEB090603), Z(MSM7088352101)
http://linked.open...iv/cisloPeriodika	19
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Kafka, Stanislav Polis, Jiří Mrkvička, Vladimír Klásek, Antonín
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Tomáše Bati ve Zlíně / Fakulta technologická
http://linked.open...dnocenehoVysledku	368092
http://linked.open...ai/riv/idVysledku	RIV/70883521:28110/08:63507052
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Pyrrolo[2,3-c]quinolones; Quinolinones; Wittig olefination; Mechanism; NMR (en)
http://linked.open.../riv/klicoveSlovo	Mechanism NMR 3-c]quinolones Pyrrolo[2 Quinolinones Wittig olefination
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[2B7F3BE5F9F3]
http://linked.open...i/riv/nazevZdroje	Tetrahedron
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	New transformations of quinolinediones Transformations of 3-hydroxy, 3-amino, and 3-thiocyanatoquinoline-2,4(1H,3H)-diones to novel heterocyclic systems
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	64
http://linked.open...iv/tvurceVysledku	Kafka, Stanislav Klásek, Antonín Mrkvička, Vladimír Polis, Jiří Košmirlj, Janez Palík, Ctirad Rosenbreierová, Veronika
http://linked.open...n/vavai/riv/zamer	Multifunctional Composite Systems Based on Natural and Synthetic Polymers
issn	0040-4020
number of pages	16 (xsd:int)
http://localhost/t...ganizacniJednotka	28110

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