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  • The work discusses the effects of polymorphism of isotactic polypropylene on its photodegradation behaviour. The starting polymer was modified by a specific α-nucleating/clarifying agent, by a specific β-nucleating agent or their combination. The samples, films of thickness 0.2 mm, were prepared via compression moulding. Differential scanning calorimetry revealed that the modification of isotactic polypropylene by a specific β-nucleating agent caused predominant formation of the trigonal β-phase. With virgin samples modified by α-nucleating agent and combination of both nucleating agents and also with neat polypropylene only monoclinic α-phase was detected. Thus the α-nucleating agent possesses higher nucleating efficiency as compared to β-nucleating agent. The samples were exposed to UV-irradiation in the interval from 0 to 240 hours. The differences in morphology were reflected in different photooxidative behaviour. Infrared spectroscopy showed that neat polyp
  • The work discusses the effects of polymorphism of isotactic polypropylene on its photodegradation behaviour. The starting polymer was modified by a specific α-nucleating/clarifying agent, by a specific β-nucleating agent or their combination. The samples, films of thickness 0.2 mm, were prepared via compression moulding. Differential scanning calorimetry revealed that the modification of isotactic polypropylene by a specific β-nucleating agent caused predominant formation of the trigonal β-phase. With virgin samples modified by α-nucleating agent and combination of both nucleating agents and also with neat polypropylene only monoclinic α-phase was detected. Thus the α-nucleating agent possesses higher nucleating efficiency as compared to β-nucleating agent. The samples were exposed to UV-irradiation in the interval from 0 to 240 hours. The differences in morphology were reflected in different photooxidative behaviour. Infrared spectroscopy showed that neat polyp (en)
  • Práce diskutuje vliv polymorfismu izotaktického polypropylenu na jeho fotodegradaci. Polypropylen byl modifikován specifickým α-nukleačním/zjasňujícím činidlem, β-nukleačním činidlem a jejich kombinací. Vzorky o tloušťce 0,2 mm byly vyrobeny lisováním. Diferenciální skenovací kalorimetrie odhalila, že modifikace polypropylenu specifickým β-nukleačním činidlem vedlo k majoritní tvorbě trigonální β-fáze. V případě čistého, α-nukleovaného a polypropylenu nukeovaného oběma činidly byly pozorována tvorba α-fáze. Lze tedy říci, že α-nukleační činidlo vykazuje vyšší účinnost než β-nukleační činidlo. Vzorky byly vystaveny UV-záření v intervalu od 0 do 240 hodin. Rozdíly v morfologii se odrazily na degradačním chování jednotlivých vzorků. Čistý polypropylen byl nejvíce citlivý k fotooxidaci, naopak tomu bylo u β-nukleovaného vzorku. (cs)
Title
  • Photodegradation of Polypropylene Containing Nucleating Agents
  • Fotodegradace polypropylenu obsahujícího nukleační činidla (cs)
  • Photodegradation of Polypropylene Containing Nucleating Agents (en)
skos:prefLabel
  • Photodegradation of Polypropylene Containing Nucleating Agents
  • Fotodegradace polypropylenu obsahujícího nukleační činidla (cs)
  • Photodegradation of Polypropylene Containing Nucleating Agents (en)
skos:notation
  • RIV/70883521:28110/08:63507028!RIV09-GA0-28110___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GP106/07/P262), Z(MSM7088352101)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 386537
http://linked.open...ai/riv/idVysledku
  • RIV/70883521:28110/08:63507028
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Photodegradation of Polypropylene Containing Nucleating Agents (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [E0B1142BEE32]
http://linked.open...v/mistoKonaniAkce
  • Salerno, Italy
http://linked.open...i/riv/mistoVydani
  • Salerno
http://linked.open...i/riv/nazevZdroje
  • PPS-24
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Commereuc, Sophie
  • Navrátilová, Jana
  • Verney, Vincent
  • Čermák, Roman
  • Raab, Miroslav
  • Mošnovská, Radka
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
http://purl.org/ne...btex#hasPublisher
  • Polymer Processing Society (IT)
https://schema.org/isbn
  • 88-7897-025-5
http://localhost/t...ganizacniJednotka
  • 28110
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