Description
| - The molecular structures of two byproducts 1,1''-diphenyl-3',4'-dihydrodispiro[indole-2,2'-furan-5',2''-indole]-3,3''(1H, 1''H)-dione(3) and 1,5'-diphenyl-4',5'-dihydro-3'H-spiro[indole-2,2'-pyrano[3,2-b]indol]-3(1H)-one (4), which accompanied the rearrangement of 3-hydroxy-3-methyl-1-phenylquinoline-2,4(1H,3H)-dione (1) to 2-hydroxy-2-methyl-1-phenyl-1,2-dihydro-3H-indol-3-one (2), have been elucidated by NMR, MS, and X-ray diffraction.
- The molecular structures of two byproducts 1,1''-diphenyl-3',4'-dihydrodispiro[indole-2,2'-furan-5',2''-indole]-3,3''(1H, 1''H)-dione(3) and 1,5'-diphenyl-4',5'-dihydro-3'H-spiro[indole-2,2'-pyrano[3,2-b]indol]-3(1H)-one (4), which accompanied the rearrangement of 3-hydroxy-3-methyl-1-phenylquinoline-2,4(1H,3H)-dione (1) to 2-hydroxy-2-methyl-1-phenyl-1,2-dihydro-3H-indol-3-one (2), have been elucidated by NMR, MS, and X-ray diffraction. (en)
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