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  • The effect of β-nucleation on structure and properties of cast films manufactured from various isotactic polypropylenes has been studied. Two commercial-available polypropylenes - homopolymer (PP) and random copolymer (rPP) - were modified by 0.03 wt.% of specific β-nucleating agent based on N,N´-dicyclohexylnaphthalene-2,6-dicarboxamide. Cast films were prepared from both starting and nucleated polypropylenes using an extrusion line consisting of a Brabender single-screw extruder, slit die and water-cooled chill-rolls. Supermolecular structure of the films was evaluated using wide-angle X-ray scattering; tensile testing was used for the preliminary measurement of mechanical properties. A significant effect of the nucleation and solidification temperature on structure and consequent properties of the films was found in both PP and rPP and is discussed in this work.
  • The effect of β-nucleation on structure and properties of cast films manufactured from various isotactic polypropylenes has been studied. Two commercial-available polypropylenes - homopolymer (PP) and random copolymer (rPP) - were modified by 0.03 wt.% of specific β-nucleating agent based on N,N´-dicyclohexylnaphthalene-2,6-dicarboxamide. Cast films were prepared from both starting and nucleated polypropylenes using an extrusion line consisting of a Brabender single-screw extruder, slit die and water-cooled chill-rolls. Supermolecular structure of the films was evaluated using wide-angle X-ray scattering; tensile testing was used for the preliminary measurement of mechanical properties. A significant effect of the nucleation and solidification temperature on structure and consequent properties of the films was found in both PP and rPP and is discussed in this work. (en)
  • Byl studován vliv β-nukleace na strukturu a vlastnosti litých fólií vyrobených z různých izotaktických polypropylenů. Dva komerčně dostupné polypropyleny - homopolymer (PP) a statistický kopolymer (rPP) - byly modifikovány specifickým β-nukleačním činidlem (N,N'-dicyklohexylnaftalen-2,6-dikarboxamid) v množství 0.03 hm.%. Lité fólie byly připraveny z čistých i nukleovaných polypropylenů pomocí vytlačovací linky skládající se z jednošnekového vytlačovacího stroje Brabender, širokoštěrbinové hlavy a vodou chlazených válců. Nadmolekulární struktura filmů byla sledována pomocí širokoúhlé rentgenografie, tahová zkouša sloužila k základnímu určení mechanických vlastností. Byl pozorován výrazný vliv nukleace a teploty chlazení na strukturu a vlastnosti fólií vyrobených z obou PP i rPP. (cs)
Title
  • Structure and properties of cast films produced form β-nucleated polypropylene
  • Structure and properties of cast films produced form β-nucleated polypropylene (en)
  • Struktura a vlastnosti lité fólie z β-nukleovaného polypropylenu (cs)
skos:prefLabel
  • Structure and properties of cast films produced form β-nucleated polypropylene
  • Structure and properties of cast films produced form β-nucleated polypropylene (en)
  • Struktura a vlastnosti lité fólie z β-nukleovaného polypropylenu (cs)
skos:notation
  • RIV/70883521:28110/06:63504614!RIV07-MSM-28110___
http://linked.open.../vavai/riv/strany
  • 345-358
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  • Z(MSM7088352101)
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  • 501969
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  • RIV/70883521:28110/06:63504614
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  • isotactic polypropylene, cast film, crystallinity, β -phase, mechanical properties (en)
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  • [1BCDCDD47BE9]
http://linked.open...i/riv/mistoVydani
  • Barcelona - Lloret de Mar, Spain
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  • 10. International Research/Expert Conference TMT 2006
http://linked.open...in/vavai/riv/obor
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  • Čermák, Roman
  • Obadal, Martin
  • Beníček, Lubomír
  • Hnidáková, Dana
http://linked.open...n/vavai/riv/zamer
number of pages
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  • University of Zagreb
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  • 9958-617-30-7
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  • 28110
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