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  • Radiation and chemical stabilities of CMPO-functionalised calix[4]arenes, promising ligands for extraction of actinides and lanthanides, were studied both in Solution and in the solid state. A comparison of the results showed that the degradation of ligands under radiolytic conditions proceeds indirectly via interactions with the solvent. The radiation stabilities in chloroform and I-octanol were systematically studied using model compounds, and the main degradation product under extraction conditions (organic phase/conc. HNO3) was characterised.
  • Radiation and chemical stabilities of CMPO-functionalised calix[4]arenes, promising ligands for extraction of actinides and lanthanides, were studied both in Solution and in the solid state. A comparison of the results showed that the degradation of ligands under radiolytic conditions proceeds indirectly via interactions with the solvent. The radiation stabilities in chloroform and I-octanol were systematically studied using model compounds, and the main degradation product under extraction conditions (organic phase/conc. HNO3) was characterised. (en)
Title
  • Radiation and chemical stability of calix[4]arene derivatives as prospective liquid-liquid extractants
  • Radiation and chemical stability of calix[4]arene derivatives as prospective liquid-liquid extractants (en)
skos:prefLabel
  • Radiation and chemical stability of calix[4]arene derivatives as prospective liquid-liquid extractants
  • Radiation and chemical stability of calix[4]arene derivatives as prospective liquid-liquid extractants (en)
skos:notation
  • RIV/68407700:21340/09:00163371!RIV10-GA0-21340___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA104/07/1242)
http://linked.open...iv/cisloPeriodika
  • 8
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 337960
http://linked.open...ai/riv/idVysledku
  • RIV/68407700:21340/09:00163371
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Extraction; Calixarene; Synthesis; Radiation; Stability; CMPO (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [0C85CC4AE794]
http://linked.open...i/riv/nazevZdroje
  • Radiochimica Acta
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 97
http://linked.open...iv/tvurceVysledku
  • John, Jan
  • Čuba, Václav
http://linked.open...ain/vavai/riv/wos
  • 000269725500006
issn
  • 0033-8230
number of pages
http://localhost/t...ganizacniJednotka
  • 21340
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