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  • This paper offers a theoretical explanation of the coupling effect phenomenon between mechanical loading and chemical reactions based on linear non-equilibrium thermodynamics and also discusses the classical method of obtaining restrictions on the phenomenological coefficients. The question whether static or dynamic loading influences biochemical processes is addressed-the necessity of dynamic loading as a stimulatory mechanism is shown. Further, the presented paper suggests that chemical and mechanical processes do not only facilitate or support one another but they may also play a triggering role for the other coupled process-some biochemical processes may need mechanical stimulation to run and vice versa as well-chemical reactions may provide energy for some mechanical processes. As an example, a detailed analysis of a model for controlled autocatalytic reproduction is presented, where the coupling effect, i.e. the influence of dynamic loading on reaction kinetics, is demonstrated.
  • This paper offers a theoretical explanation of the coupling effect phenomenon between mechanical loading and chemical reactions based on linear non-equilibrium thermodynamics and also discusses the classical method of obtaining restrictions on the phenomenological coefficients. The question whether static or dynamic loading influences biochemical processes is addressed-the necessity of dynamic loading as a stimulatory mechanism is shown. Further, the presented paper suggests that chemical and mechanical processes do not only facilitate or support one another but they may also play a triggering role for the other coupled process-some biochemical processes may need mechanical stimulation to run and vice versa as well-chemical reactions may provide energy for some mechanical processes. As an example, a detailed analysis of a model for controlled autocatalytic reproduction is presented, where the coupling effect, i.e. the influence of dynamic loading on reaction kinetics, is demonstrated. (en)
Title
  • Coupling Effect between Mechanical Loading and Chemical Reactions
  • Coupling Effect between Mechanical Loading and Chemical Reactions (en)
skos:prefLabel
  • Coupling Effect between Mechanical Loading and Chemical Reactions
  • Coupling Effect between Mechanical Loading and Chemical Reactions (en)
skos:notation
  • RIV/68407700:21340/09:00158815!RIV10-MSM-21340___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA106/08/0557), Z(AV0Z20760514), Z(MSM6840770010)
http://linked.open...iv/cisloPeriodika
  • 44
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 308462
http://linked.open...ai/riv/idVysledku
  • RIV/68407700:21340/09:00158815
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • coupling; dynamic loading; reaction kinetics (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [6FC980296001]
http://linked.open...i/riv/nazevZdroje
  • JOURNAL OF PHYSICAL CHEMISTRY B
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 113
http://linked.open...iv/tvurceVysledku
  • Klika, Václav
http://linked.open...ain/vavai/riv/wos
  • 000271105600019
http://linked.open...n/vavai/riv/zamer
issn
  • 1520-6106
number of pages
http://localhost/t...ganizacniJednotka
  • 21340
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