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  • Cr-Nb-Al-N coatings with Al content from 0 to 12 at.% were deposited by d.c. reactive magnetron sputtering. The coatings were annealed in protective atmosphere at 800 and 900 degrees C for 1 h and exposed to air at 800,900 and 1200 degrees C for different times. The chemical composition, structure, microstructure, hardness and adhesive/cohesive strength of the coatings, in as-deposited and annealed conditions, were investigated and the oxidation resistance was evaluated. As expected, the Al content increased gradually in the coating with increasing power density in the Al target; nitrogen was kept approximately constant. All coatings exhibited columnar cross section morphology and fcc NaCl-type B1 phase structure. After thermal annealing, an increase in the grain size and a decrease in the lattice parameter were observed, which led to either a decrease in the hardness or lower adhesion/cohesion strength than the as-deposited coatings. The onset oxidation temperature was approx. 900 degrees C for all coatings. High Al content coatings showed minimum oxidation when exposed to 800 degrees C for 2 h and to 900 degrees C for 0.5 h in air. The Al-free and low Al coatings exhibited lower oxidation resistance; Cr2O3 and CrNbO4 coexisting together although signs of the cubic nitride phase were still detected. The increase of Al was beneficial to the improvement of the thermal stability and oxidation resistance of the Cr-Nb-Al-N coatings.
  • Cr-Nb-Al-N coatings with Al content from 0 to 12 at.% were deposited by d.c. reactive magnetron sputtering. The coatings were annealed in protective atmosphere at 800 and 900 degrees C for 1 h and exposed to air at 800,900 and 1200 degrees C for different times. The chemical composition, structure, microstructure, hardness and adhesive/cohesive strength of the coatings, in as-deposited and annealed conditions, were investigated and the oxidation resistance was evaluated. As expected, the Al content increased gradually in the coating with increasing power density in the Al target; nitrogen was kept approximately constant. All coatings exhibited columnar cross section morphology and fcc NaCl-type B1 phase structure. After thermal annealing, an increase in the grain size and a decrease in the lattice parameter were observed, which led to either a decrease in the hardness or lower adhesion/cohesion strength than the as-deposited coatings. The onset oxidation temperature was approx. 900 degrees C for all coatings. High Al content coatings showed minimum oxidation when exposed to 800 degrees C for 2 h and to 900 degrees C for 0.5 h in air. The Al-free and low Al coatings exhibited lower oxidation resistance; Cr2O3 and CrNbO4 coexisting together although signs of the cubic nitride phase were still detected. The increase of Al was beneficial to the improvement of the thermal stability and oxidation resistance of the Cr-Nb-Al-N coatings. (en)
Title
  • High temperature properties of the Cr-Nb-Al-N coatings with increasing Al contents
  • High temperature properties of the Cr-Nb-Al-N coatings with increasing Al contents (en)
skos:prefLabel
  • High temperature properties of the Cr-Nb-Al-N coatings with increasing Al contents
  • High temperature properties of the Cr-Nb-Al-N coatings with increasing Al contents (en)
skos:notation
  • RIV/68407700:21230/13:00205685!RIV14-MSM-21230___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM6840770038)
http://linked.open...iv/cisloPeriodika
  • August
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 77371
http://linked.open...ai/riv/idVysledku
  • RIV/68407700:21230/13:00205685
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Cr-Nb-Al-N coatings; Mechanical properties; Thermal stability; Oxidation resistance; High temperature (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [EB1163BCB104]
http://linked.open...i/riv/nazevZdroje
  • Surface and Coatings Technology
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 228
http://linked.open...iv/tvurceVysledku
  • Cavaleiro, A.
  • Evaristo, M.
  • Polcar, Tomáš
  • Li, W.Z.
http://linked.open...ain/vavai/riv/wos
  • 000321797100022
http://linked.open...n/vavai/riv/zamer
issn
  • 0257-8972
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.surfcoat.2013.04.027
http://localhost/t...ganizacniJednotka
  • 21230
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