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  • A theoretical model of the nucleation of portlandite is proposed, and the critical size of a portlandite cluster and the energy barrier of nucleation are determined. The steady state nucleation rate and the time lag of the nucleation of portlandite are estimated for a pure solution of Ca(OH)2 in water. Possible connections with the corresponding properties for cement paste are discussed. A new method is developed for experimentally determining the concentration of Ca2+ ions during the initial stage of hydration of a cement paste. The time dependence of Ca2+ ions is measured for various water-to-cement ratio values. The results are discussed from the point of view of existing models of the induction period.
  • A theoretical model of the nucleation of portlandite is proposed, and the critical size of a portlandite cluster and the energy barrier of nucleation are determined. The steady state nucleation rate and the time lag of the nucleation of portlandite are estimated for a pure solution of Ca(OH)2 in water. Possible connections with the corresponding properties for cement paste are discussed. A new method is developed for experimentally determining the concentration of Ca2+ ions during the initial stage of hydration of a cement paste. The time dependence of Ca2+ ions is measured for various water-to-cement ratio values. The results are discussed from the point of view of existing models of the induction period. (en)
Title
  • Physical and Chemical Aspects of the Nucleation of Cement-Based Materials
  • Physical and Chemical Aspects of the Nucleation of Cement-Based Materials (en)
skos:prefLabel
  • Physical and Chemical Aspects of the Nucleation of Cement-Based Materials
  • Physical and Chemical Aspects of the Nucleation of Cement-Based Materials (en)
skos:notation
  • RIV/68407700:21110/12:00211710!RIV14-MSM-21110___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • S, Z(AV0Z10100521), Z(MSM6840770003)
http://linked.open...iv/cisloPeriodika
  • 6/2012
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 158635
http://linked.open...ai/riv/idVysledku
  • RIV/68407700:21110/12:00211710
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • cement paste; induction period; calcium concentration; nucleation rate; time lag (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [87F9370FB41C]
http://linked.open...i/riv/nazevZdroje
  • Acta Polytechnica
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 52
http://linked.open...iv/tvurceVysledku
  • Demo, Pavel
  • Sveshnikov, Alexey
  • Tichá, Petra
  • Hošková, Šárka
  • Ladman, David
http://linked.open...n/vavai/riv/zamer
issn
  • 1210-2709
number of pages
http://localhost/t...ganizacniJednotka
  • 21110
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