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  • The process of alkali activation of fly ash and metakaolin is examined in the view of micromechanics. Elasticity is predicted via semi-analytical homogenization methods, using a combination of intrinsic elastic properties obtained from nanoindentation, evolving volume fractions and percolation theory. A new quantitative model for volume fraction is formulated, distinguishing the evolution of unreacted aluminosilicate material, solid gel particles of N-A-S-H gel, and open porosity, which is partially filled with the activator. The stiffening of N-A-S-H gel is modeled by increasing the fraction of solid gel particles. Their packing density and intrinsic elasticity differ in N-A-S-H gels synthesized from both activated materials. The low ability of N-A-S-H gel to bind water chemically explains the high porosity of Ca-deficient activated materials.
  • The process of alkali activation of fly ash and metakaolin is examined in the view of micromechanics. Elasticity is predicted via semi-analytical homogenization methods, using a combination of intrinsic elastic properties obtained from nanoindentation, evolving volume fractions and percolation theory. A new quantitative model for volume fraction is formulated, distinguishing the evolution of unreacted aluminosilicate material, solid gel particles of N-A-S-H gel, and open porosity, which is partially filled with the activator. The stiffening of N-A-S-H gel is modeled by increasing the fraction of solid gel particles. Their packing density and intrinsic elasticity differ in N-A-S-H gels synthesized from both activated materials. The low ability of N-A-S-H gel to bind water chemically explains the high porosity of Ca-deficient activated materials. (en)
Title
  • Micromechanical multiscale model for alkali activation of fly ash and metakaolin
  • Micromechanical multiscale model for alkali activation of fly ash and metakaolin (en)
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  • Micromechanical multiscale model for alkali activation of fly ash and metakaolin
  • Micromechanical multiscale model for alkali activation of fly ash and metakaolin (en)
skos:notation
  • RIV/68407700:21110/11:00180836!RIV12-GA0-21110___
http://linked.open...avai/riv/aktivita
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  • P(GA103/09/1748), P(GAP104/10/2344)
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  • 20
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  • 212319
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  • RIV/68407700:21110/11:00180836
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  • alkali-activation; fly ash; metakaolin; micromechanics; nanoindentation; N-A-S-H gel (en)
http://linked.open.../riv/klicoveSlovo
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  • US - Spojené státy americké
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  • [6CF41C606BC6]
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  • Journal of Materials Science
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  • 46
http://linked.open...iv/tvurceVysledku
  • Hlaváček, Petr
  • Kopecký, Lubomír
  • Němeček, Jiří
  • Škvára, F.
  • Šulc, Rostislav
  • Šmilauer, Vít
http://linked.open...ain/vavai/riv/wos
  • 000293137500009
issn
  • 0022-2461
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s10853-011-5601-x
http://localhost/t...ganizacniJednotka
  • 21110
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