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  • In this work we report on the local structure of Ti in (SrTiO3)-O-16 (STO16) and (SrTiO3)-O-18 (STO18) investigated in the low temperature range (6-300 K) by extended x-ray absorption fine structure and x-ray absorption near edge structure (XANES) spectroscopy at Ti K-edge and by optical second harmonic generation (SHG). By comparing XANES of STO16 and STO18 we have identified the isotopic effect which produces at T < 100K a noticeable difference in the measured mean square relative displacements (MSRD) of Ti-O-1 bonds: while STO16 follow the expected Einstein-like behavior, for STO18 we have measured an increase of MSRD values with decreasing temperature. This is an indication of an increasing off-center position of the Ti atoms in the TiO6 octahedra.
  • In this work we report on the local structure of Ti in (SrTiO3)-O-16 (STO16) and (SrTiO3)-O-18 (STO18) investigated in the low temperature range (6-300 K) by extended x-ray absorption fine structure and x-ray absorption near edge structure (XANES) spectroscopy at Ti K-edge and by optical second harmonic generation (SHG). By comparing XANES of STO16 and STO18 we have identified the isotopic effect which produces at T < 100K a noticeable difference in the measured mean square relative displacements (MSRD) of Ti-O-1 bonds: while STO16 follow the expected Einstein-like behavior, for STO18 we have measured an increase of MSRD values with decreasing temperature. This is an indication of an increasing off-center position of the Ti atoms in the TiO6 octahedra. (en)
Title
  • Local structure studies of SrTi16O3 and SrTi18O3./sub
  • Local structure studies of SrTi16O3 and SrTi18O3./sub (en)
skos:prefLabel
  • Local structure studies of SrTi16O3 and SrTi18O3./sub
  • Local structure studies of SrTi16O3 and SrTi18O3./sub (en)
skos:notation
  • RIV/68378271:_____/14:00441459!RIV15-GA0-68378271
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  • I, P(GAP108/12/1941)
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  • 4
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  • 26467
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  • RIV/68378271:_____/14:00441459
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  • near-edge structure; K phase-transition; soft phonon modes; strontium-titanate (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • 89
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  • Dejneka, Alexandr
  • Trepakov, Vladimír
  • Rocca, F.
  • Anspoks, A.
  • Bocharov, D.
  • Itoh, M.
  • Purans, J.
  • Sarakovskis, A.
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  • 000333449400003
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  • 0031-8949
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  • 10.1088/0031-8949/89/04/044002
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