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  • This study focuses on the synthesis, characterization, and kinetics of substitution reaction of new uranyl Schiff base complexes prepared in a crystalline state as well as in a form of nanoparticles. The compounds were characterized by UV–vis, 1H NMR, cyclic voltammetry and X-ray crystallography. X-ray crystallography revealed coordination of the uranyl by the tetradentate Schiff base ligand and one solvent molecule, resulting in seven-coordinated uranium. The second-order rate constants at four temperatures and the activation parameters revealed an associative mechanism for all corresponding complexes. Anticancer activity of the nano uranyl Schiff base complexes against cancer cell lines (Jurkat) was also studied.
  • This study focuses on the synthesis, characterization, and kinetics of substitution reaction of new uranyl Schiff base complexes prepared in a crystalline state as well as in a form of nanoparticles. The compounds were characterized by UV–vis, 1H NMR, cyclic voltammetry and X-ray crystallography. X-ray crystallography revealed coordination of the uranyl by the tetradentate Schiff base ligand and one solvent molecule, resulting in seven-coordinated uranium. The second-order rate constants at four temperatures and the activation parameters revealed an associative mechanism for all corresponding complexes. Anticancer activity of the nano uranyl Schiff base complexes against cancer cell lines (Jurkat) was also studied. (en)
Title
  • Kinetics of thermal decomposition and kinetics of substitution reaction of nano uranyl Schiff base complexes
  • Kinetics of thermal decomposition and kinetics of substitution reaction of nano uranyl Schiff base complexes (en)
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  • Kinetics of thermal decomposition and kinetics of substitution reaction of nano uranyl Schiff base complexes
  • Kinetics of thermal decomposition and kinetics of substitution reaction of nano uranyl Schiff base complexes (en)
skos:notation
  • RIV/68378271:_____/14:00440548!RIV15-GA0-68378271
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  • I, P(GAP204/11/0809)
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  • 12
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  • 24258
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  • RIV/68378271:_____/14:00440548
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  • uranyl; Schiff base; kinetics; anticancer activity (en)
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  • US - Spojené státy americké
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  • [746DF0A9933A]
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  • International Journal of Chemical Kinetics
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  • 46
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  • Dušek, Michal
  • Eigner, Václav
  • Asadi, Z.
  • Zeinali, A.
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  • 000344389600002
issn
  • 0538-8066
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/kin.20881
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