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  • In this work eld-sweep electron spin echo and pulsed electron nuclear double resonance study of the silicon carbide (SiC) nanoparticles (np-SiC) of di erent sizes is presented. Nitrogen (N) triplet lines due to the isolated N donor state was observed in np-SiC with grain size d > 100 nm. With a decrease of the particle size up to 50 nm the N triplet lines transforms into one single exchange line due to the delocalization of the donor wave function caused by the size con nement e ect. Along with N donors the carbon vacancy (VC) located in cubic phase was observed in np-SiC with d < 100 nm. The further decrease of the grain size to d < 50 nm leads to the appearance of the VC located in hexagonal crystalline phase and carbon dangling bonds located in the carbon excess phase of np-SiC. The fact that only N donor center at k2 quasi-cubic position substituting Si site was observed in the eld-sweep electron spin echo and pulsed electron.
  • In this work eld-sweep electron spin echo and pulsed electron nuclear double resonance study of the silicon carbide (SiC) nanoparticles (np-SiC) of di erent sizes is presented. Nitrogen (N) triplet lines due to the isolated N donor state was observed in np-SiC with grain size d > 100 nm. With a decrease of the particle size up to 50 nm the N triplet lines transforms into one single exchange line due to the delocalization of the donor wave function caused by the size con nement e ect. Along with N donors the carbon vacancy (VC) located in cubic phase was observed in np-SiC with d < 100 nm. The further decrease of the grain size to d < 50 nm leads to the appearance of the VC located in hexagonal crystalline phase and carbon dangling bonds located in the carbon excess phase of np-SiC. The fact that only N donor center at k2 quasi-cubic position substituting Si site was observed in the eld-sweep electron spin echo and pulsed electron. (en)
Title
  • Pulsed EPR and ENDOR study of SiC nanopowders
  • Pulsed EPR and ENDOR study of SiC nanopowders (en)
skos:prefLabel
  • Pulsed EPR and ENDOR study of SiC nanopowders
  • Pulsed EPR and ENDOR study of SiC nanopowders (en)
skos:notation
  • RIV/68378271:_____/14:00439631!RIV15-GA0-68378271
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  • I, P(GP13-06697P), P(LM2011029)
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  • 40896
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  • RIV/68378271:_____/14:00439631
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  • EPR; ENDOR; SiC nanopowders; size effect (en)
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  • [67BF331AA460]
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  • Wisla
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  • Warsaw
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  • Acta Physica Polonica A, vol. 126, 2014, č. 5
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  • Savchenko, Dariia
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issn
  • 0587-4246
number of pages
http://bibframe.org/vocab/doi
  • 10.12693/APhysPolA.126.1063
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  • Polska Akademia Nauk
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