About: Selective laser spectroscopy of Mn4+-Mn4+ pair centers in SrTiO3 crystal     Goto   Sponge   NotDistinct   Permalink

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  • Zero-phonon lines of a pair center of Mn4+ ions are observed in the luminescence and luminescence-excitation spectra of SrTiO3:Mn crystal. Based on the experimental data, the energy-level structure of the ground state |4 A 2g ,4 A 2g > and excited state |4 A 2g ,2 E g > of the Mn4+-Mn4+ pair center is constructed. It is shown that the exchange interaction in the ground state of the Mn4+-Mn4+ pair is antiferromagnetic. Energies of the levels are calculated assuming that the pair is formed by Mn4+ ions occupying neighboring octahedral positions of Ti4+ ions along the [110] axis. Experimental values of the exchange integral in the ground state |4 A 2g ,4 A 2g > and energies of spin multiplets in the excited state |4 A 2g ,2 E g > agree well with calculation of the exchange interaction carried out within the framework of the channel model with the parameters J ξη = 32 cm4-1 and J ζζ = 45.5 cm4-1.
  • Zero-phonon lines of a pair center of Mn4+ ions are observed in the luminescence and luminescence-excitation spectra of SrTiO3:Mn crystal. Based on the experimental data, the energy-level structure of the ground state |4 A 2g ,4 A 2g > and excited state |4 A 2g ,2 E g > of the Mn4+-Mn4+ pair center is constructed. It is shown that the exchange interaction in the ground state of the Mn4+-Mn4+ pair is antiferromagnetic. Energies of the levels are calculated assuming that the pair is formed by Mn4+ ions occupying neighboring octahedral positions of Ti4+ ions along the [110] axis. Experimental values of the exchange integral in the ground state |4 A 2g ,4 A 2g > and energies of spin multiplets in the excited state |4 A 2g ,2 E g > agree well with calculation of the exchange interaction carried out within the framework of the channel model with the parameters J ξη = 32 cm4-1 and J ζζ = 45.5 cm4-1. (en)
Title
  • Selective laser spectroscopy of Mn4+-Mn4+ pair centers in SrTiO3 crystal
  • Selective laser spectroscopy of Mn4+-Mn4+ pair centers in SrTiO3 crystal (en)
skos:prefLabel
  • Selective laser spectroscopy of Mn4+-Mn4+ pair centers in SrTiO3 crystal
  • Selective laser spectroscopy of Mn4+-Mn4+ pair centers in SrTiO3 crystal (en)
skos:notation
  • RIV/68378271:_____/14:00436810!RIV15-GA0-68378271
http://linked.open...avai/riv/aktivita
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  • I, P(GAP108/12/1941), P(TA01010517)
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  • 6
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  • 44296
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  • RIV/68378271:_____/14:00436810
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  • Zero-phonon; luminescence; antiferromagnetic (en)
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  • RU - Ruská federace
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  • [8EB8348878F1]
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  • Optics and Spectroscopy
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  • 116
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  • Dejneka, Alexandr
  • Trepakov, Vladimír
  • Yusupov, R. V.
  • Eremin, M. V.
  • Gilyazov, L. R.
  • Nikitin, S. I.
http://linked.open...ain/vavai/riv/wos
  • 000339948200001
issn
  • 0030-400X
number of pages
http://bibframe.org/vocab/doi
  • 10.1134/S0030400X14060071
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