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  • Model of nucleation on active centers is applied to formation of folded chain crystals of polyethylene at low supercooling. Nucleation rate and the total number of nuclei are determined by numerical solution of kinetic equations. Thermodynamic and kinetic parameters were chosen to get the coincidence with experimental data for the total number of nuclei and the size distribution of nuclei as a function of time. Nucleation rates for various cluster sizes and the exhaustion of active centers due to the phase transition process were determined. It is shown that the number of exhausted active centers, on which crystalline nuclei are formed, increases with time.
  • Model of nucleation on active centers is applied to formation of folded chain crystals of polyethylene at low supercooling. Nucleation rate and the total number of nuclei are determined by numerical solution of kinetic equations. Thermodynamic and kinetic parameters were chosen to get the coincidence with experimental data for the total number of nuclei and the size distribution of nuclei as a function of time. Nucleation rates for various cluster sizes and the exhaustion of active centers due to the phase transition process were determined. It is shown that the number of exhausted active centers, on which crystalline nuclei are formed, increases with time. (en)
Title
  • Crystal nucleation kinetics of polyethylene on active centers
  • Crystal nucleation kinetics of polyethylene on active centers (en)
skos:prefLabel
  • Crystal nucleation kinetics of polyethylene on active centers
  • Crystal nucleation kinetics of polyethylene on active centers (en)
skos:notation
  • RIV/68378271:_____/14:00432521!RIV15-GA0-68378271
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP108/12/0891)
http://linked.open...iv/cisloPeriodika
  • Sep
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 9288
http://linked.open...ai/riv/idVysledku
  • RIV/68378271:_____/14:00432521
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • nucleation; polyethylene; crystallization (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [CE8E290D703A]
http://linked.open...i/riv/nazevZdroje
  • Journal of Crystal Growth
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 401
http://linked.open...iv/tvurceVysledku
  • Demo, Pavel
  • Kožíšek, Zdeněk
  • Okada, K.
  • Hikosaka, M.
http://linked.open...ain/vavai/riv/wos
  • 000340001800011
issn
  • 0022-0248
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.jcrysgro.2014.02.013
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