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  • YAlO3:Bi ceramics prepared from the nanopowders synthesized by the sol–gel (Pechini) method are studied at 8–400 K by the time-resolved spectroscopy methods. An intense dominant ultraviolet luminescence of YAlO3:Bi is shown to arise from the radiative decay of the metastable and radiative minima of the triplet relaxed excited state (RES) of Bi3+ centers related to the 3P0, 3P1 levels of a free Bi3+ ion, respectively. The energy separation between the radiative and metastable minima, and the rates of the radiative and nonradiative transitions from these minima, are determined.
  • YAlO3:Bi ceramics prepared from the nanopowders synthesized by the sol–gel (Pechini) method are studied at 8–400 K by the time-resolved spectroscopy methods. An intense dominant ultraviolet luminescence of YAlO3:Bi is shown to arise from the radiative decay of the metastable and radiative minima of the triplet relaxed excited state (RES) of Bi3+ centers related to the 3P0, 3P1 levels of a free Bi3+ ion, respectively. The energy separation between the radiative and metastable minima, and the rates of the radiative and nonradiative transitions from these minima, are determined. (en)
Title
  • Time-resolved photoluminescence and excited state structure of Bi3+ center in YAlO3./sub
  • Time-resolved photoluminescence and excited state structure of Bi3+ center in YAlO3./sub (en)
skos:prefLabel
  • Time-resolved photoluminescence and excited state structure of Bi3+ center in YAlO3./sub
  • Time-resolved photoluminescence and excited state structure of Bi3+ center in YAlO3./sub (en)
skos:notation
  • RIV/68378271:_____/14:00432028!RIV15-GA0-68378271
http://linked.open...avai/riv/aktivita
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  • I, P(GAP204/12/0805)
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  • 10
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  • 50591
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  • RIV/68378271:_____/14:00432028
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  • Bi3+-doped aluminum perovskite; time-resolved luminescence; scintillation materials (en)
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  • NL - Nizozemsko
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  • [AF038EF6A6C8]
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  • Optical Materials
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  • 36
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  • Mihóková, Eva
  • Nikl, Martin
  • Zazubovich, S.
  • Krasnikov, A.
  • Shalapska, T.
  • Suchocki, A.
  • Lipinska, L.
  • Zhydachevskii, Ya.
http://linked.open...ain/vavai/riv/wos
  • 000338406300020
issn
  • 0925-3467
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.optmat.2014.01.030
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