About: Low-dimensional compounds containing cyanide groups. XXVI. (Dicyanamido-κN1)bis(5,5'-dimethyl-2,2'-bipyridine-κ2N,N')copper(II) complexes with tetrafluoroborate and perchlorate anions     Goto   Sponge   NotDistinct   Permalink

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Description
  • The title compounds are isomorphous and consist of [Cu{N(CN)2}(mbpy)2]+ cations (mbpy is 5,50-dimethyl-2,20-bipyridine) and BF4 or ClO4 anions. The CuII cations in both structures are five-coordinated in distorted trigonal bipyramidal environments by four N atoms of two mbpy ligands and one N atom of the dicyanamide anion, which is coordinated in a monodentate manner in the equatorial plane. The work presents detailed crystallographic structures of both compounds and their comparison.
  • The title compounds are isomorphous and consist of [Cu{N(CN)2}(mbpy)2]+ cations (mbpy is 5,50-dimethyl-2,20-bipyridine) and BF4 or ClO4 anions. The CuII cations in both structures are five-coordinated in distorted trigonal bipyramidal environments by four N atoms of two mbpy ligands and one N atom of the dicyanamide anion, which is coordinated in a monodentate manner in the equatorial plane. The work presents detailed crystallographic structures of both compounds and their comparison. (en)
Title
  • Low-dimensional compounds containing cyanide groups. XXVI. (Dicyanamido-κN1)bis(5,5'-dimethyl-2,2'-bipyridine-κ2N,N')copper(II) complexes with tetrafluoroborate and perchlorate anions
  • Low-dimensional compounds containing cyanide groups. XXVI. (Dicyanamido-κN1)bis(5,5'-dimethyl-2,2'-bipyridine-κ2N,N')copper(II) complexes with tetrafluoroborate and perchlorate anions (en)
skos:prefLabel
  • Low-dimensional compounds containing cyanide groups. XXVI. (Dicyanamido-κN1)bis(5,5'-dimethyl-2,2'-bipyridine-κ2N,N')copper(II) complexes with tetrafluoroborate and perchlorate anions
  • Low-dimensional compounds containing cyanide groups. XXVI. (Dicyanamido-κN1)bis(5,5'-dimethyl-2,2'-bipyridine-κ2N,N')copper(II) complexes with tetrafluoroborate and perchlorate anions (en)
skos:notation
  • RIV/68378271:_____/13:00421119!RIV14-AV0-68378271
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I
http://linked.open...iv/cisloPeriodika
  • 11
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 85493
http://linked.open...ai/riv/idVysledku
  • RIV/68378271:_____/13:00421119
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • low dimensional compounds; cyanide group; structure determination; x-ray diffraction (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DK - Dánské království
http://linked.open...ontrolniKodProRIV
  • [AE71F6287150]
http://linked.open...i/riv/nazevZdroje
  • Acta Crystallographica. C - Crystal Structure Communications
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 69
http://linked.open...iv/tvurceVysledku
  • Dušek, Michal
  • Potočňák, I.
  • Burčák, M.
http://linked.open...ain/vavai/riv/wos
  • 000326651300032
issn
  • 0108-2701
number of pages
http://bibframe.org/vocab/doi
  • 10.1107/S0108270113027091
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