About: A novel amido–pyrophosphate Mnll chelate complex with the synthetic ligand O{P(O)[NHC(CH3)3]2}2 (L): [Mn(L)2{OC(H)N(CH3)2}2]Cl2 . 2H2O

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: A novel amido–pyrophosphate Mnll chelate complex with the synthetic ligand O{P(O)[NHC(CH3)3]2}2 (L): [Mn(L)2{OC(H)N(CH3)2}2]Cl2 . 2H2O Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The title complex is the first example of a bis-chelate amido-pyrophosphate (pyrophosphoramide) complex containing an O[P(O)(NH)2]2 fragment. Its asymmetric unit contains half of the complex dication, one chloride anion and one water molecule. The MnII atom, located on an inversion centre, is octahedrally coordinated. Structural features, such as the P O bond lengths and the planarity of the chelate ring, are compared with those of previously reported complexes with six-membered chelates involving the fragments C(O)NHP(O), (X)NP(O) [X = C(O), C(S), S(O)2 and P(O)] and O[P(O)(N)2]2. The extended structure of the title complex involves a linear aggregate mediated by hydrogen bonds, in which the chloride anion is an acceptor in two additional O—H...Cl hydrogen bonds. The title complex is the first example of a bis-chelate amido-pyrophosphate (pyrophosphoramide) complex containing an O[P(O)(NH)2]2 fragment. Its asymmetric unit contains half of the complex dication, one chloride anion and one water molecule. The MnII atom, located on an inversion centre, is octahedrally coordinated. Structural features, such as the P O bond lengths and the planarity of the chelate ring, are compared with those of previously reported complexes with six-membered chelates involving the fragments C(O)NHP(O), (X)NP(O) [X = C(O), C(S), S(O)2 and P(O)] and O[P(O)(N)2]2. The extended structure of the title complex involves a linear aggregate mediated by hydrogen bonds, in which the chloride anion is an acceptor in two additional O—H...Cl hydrogen bonds. (en)
Title	A novel amido–pyrophosphate Mnll chelate complex with the synthetic ligand O{P(O)[NHC(CH3)3]2}2 (L): [Mn(L)2{OC(H)N(CH3)2}2]Cl2 . 2H2O A novel amido–pyrophosphate Mnll chelate complex with the synthetic ligand O{P(O)[NHC(CH3)3]2}2 (L): [Mn(L)2{OC(H)N(CH3)2}2]Cl2 . 2H2O (en)
skos:prefLabel	A novel amido–pyrophosphate Mnll chelate complex with the synthetic ligand O{P(O)[NHC(CH3)3]2}2 (L): [Mn(L)2{OC(H)N(CH3)2}2]Cl2 . 2H2O A novel amido–pyrophosphate Mnll chelate complex with the synthetic ligand O{P(O)[NHC(CH3)3]2}2 (L): [Mn(L)2{OC(H)N(CH3)2}2]Cl2 . 2H2O (en)
skos:notation	RIV/68378271:_____/13:00398666!RIV14-AV0-68378271
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(AV0Z10100521)
http://linked.open...iv/cisloPeriodika	Mar
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Fejfarová, Karla Dušek, Michal
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Fyzikální ústav AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	58897
http://linked.open...ai/riv/idVysledku	RIV/68378271:_____/13:00398666
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	pyrophosphate; structure analysis; hydrogen bonds (en)
http://linked.open.../riv/klicoveSlovo	pyrophosphate hydrogen bonds structure analysis
http://linked.open...odStatuVydavatele	DK - Dánské království
http://linked.open...ontrolniKodProRIV	[373F46F66C0B]
http://linked.open...i/riv/nazevZdroje	Acta Crystallographica. C - Crystal Structure Communications
http://linked.open...in/vavai/riv/obor	BM
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	69
http://linked.open...iv/tvurceVysledku	Dušek, Michal Fejfarová, Karla Pourayoubi, M. Tarahhomi, A.
http://linked.open...ain/vavai/riv/wos	000315648600005
http://linked.open...n/vavai/riv/zamer	Physics and technology of nanostructures, surfaces and thin films
issn	0108-2701
number of pages	4 (xsd:int)
http://bibframe.org/vocab/doi	10.1107/S0108270113000814

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 48 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software