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  • This work deals with homogeneous crystal nucleation from supercooled melt and supersaturated solution in confined systems. Kinetic equations describing crystal nucleation (including depletion of the mother phase) are solved numerically to determine the size distribution of nuclei, nucleation rate, and the total number of nuclei. These basic characteristics of nucleation process are compared with the solution of the standard model, when the condition within the liquid does not change in time. Depletion of the liquid in confined volume influences the formation of crystal nuclei at a lower energy barrier of nucleation. In contrast to the standard model the number of nuclei and the nucleation rate as a function of time reach some maxima and then decrease.
  • This work deals with homogeneous crystal nucleation from supercooled melt and supersaturated solution in confined systems. Kinetic equations describing crystal nucleation (including depletion of the mother phase) are solved numerically to determine the size distribution of nuclei, nucleation rate, and the total number of nuclei. These basic characteristics of nucleation process are compared with the solution of the standard model, when the condition within the liquid does not change in time. Depletion of the liquid in confined volume influences the formation of crystal nuclei at a lower energy barrier of nucleation. In contrast to the standard model the number of nuclei and the nucleation rate as a function of time reach some maxima and then decrease. (en)
Title
  • Crystal nucleation kinetics in confined systems
  • Crystal nucleation kinetics in confined systems (en)
skos:prefLabel
  • Crystal nucleation kinetics in confined systems
  • Crystal nucleation kinetics in confined systems (en)
skos:notation
  • RIV/68378271:_____/13:00391757!RIV14-GA0-68378271
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP108/12/0891)
http://linked.open...iv/cisloPeriodika
  • 12
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 67390
http://linked.open...ai/riv/idVysledku
  • RIV/68378271:_____/13:00391757
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • nucleation; phase transtion (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [C2651F322E94]
http://linked.open...i/riv/nazevZdroje
  • CrystEngComm
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 15
http://linked.open...iv/tvurceVysledku
  • Kožíšek, Zdeněk
http://linked.open...ain/vavai/riv/wos
  • 000315410600013
issn
  • 1466-8033
number of pages
http://bibframe.org/vocab/doi
  • 10.1039/c2ce26497h
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