About: Synthesis, spectral characterization, and crystal structure of mononuclear mercury(II) complex [Hg((3,4-MeO-Bza)2En)I2]

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About: Synthesis, spectral characterization, and crystal structure of mononuclear mercury(II) complex [Hg((3,4-MeO-Bza)2En)I2] Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Mercury(II) complex, [Hg((3,4-MeO-Bza)2En)I2] , where (3,4-MeO-Bza)2En = N,N'-bis(3,4-dimethoxybenzaldehyde)ethylenediimine, has been synthesized from the reaction of HgI2 with (3,4-Me-Bza)2En in methanol as solvent at 50°C. It was characterized by elemental analysis (CHN), 1H-NMR spectroscopy and confirmed by single-crystal X-ray diffraction analysis. The complex crystallizes in the monoclinic system, with space group P21/c, having one symmetry-independent Hg2+ ion coordinated in a distorted tetrahedral geometry by two N atoms of the Schiff base ligand and by two I atoms. The Schiff ba se ligand (3,4-MeO-Bza)2En acts as a chelating ligand and coordinates via two N atoms to the mercury center. Mercury(II) complex, [Hg((3,4-MeO-Bza)2En)I2] , where (3,4-MeO-Bza)2En = N,N'-bis(3,4-dimethoxybenzaldehyde)ethylenediimine, has been synthesized from the reaction of HgI2 with (3,4-Me-Bza)2En in methanol as solvent at 50°C. It was characterized by elemental analysis (CHN), 1H-NMR spectroscopy and confirmed by single-crystal X-ray diffraction analysis. The complex crystallizes in the monoclinic system, with space group P21/c, having one symmetry-independent Hg2+ ion coordinated in a distorted tetrahedral geometry by two N atoms of the Schiff base ligand and by two I atoms. The Schiff ba se ligand (3,4-MeO-Bza)2En acts as a chelating ligand and coordinates via two N atoms to the mercury center. (en)
Title	Synthesis, spectral characterization, and crystal structure of mononuclear mercury(II) complex [Hg((3,4-MeO-Bza)2En)I2] Synthesis, spectral characterization, and crystal structure of mononuclear mercury(II) complex [Hg((3,4-MeO-Bza)2En)I2] (en)
skos:prefLabel	Synthesis, spectral characterization, and crystal structure of mononuclear mercury(II) complex [Hg((3,4-MeO-Bza)2En)I2] Synthesis, spectral characterization, and crystal structure of mononuclear mercury(II) complex [Hg((3,4-MeO-Bza)2En)I2] (en)
skos:notation	RIV/68378271:_____/13:00391678!RIV14-GA0-68378271
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GAP204/11/0809), Z(AV0Z10100521)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Fejfarová, Karla Dušek, Michal
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Fyzikální ústav AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	109567
http://linked.open...ai/riv/idVysledku	RIV/68378271:_____/13:00391678
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	mercury (II); Schiff base; single crystal; structure analysis (en)
http://linked.open.../riv/klicoveSlovo	single crystal Schiff base mercury (II) structure analysis
http://linked.open...odStatuVydavatele	RU - Ruská federace
http://linked.open...ontrolniKodProRIV	[8BB8E23E3365]
http://linked.open...i/riv/nazevZdroje	Russian Journal of Coordination Chemistry
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Absorption, beam homogeneity and varying irradiated volume corrections in multidomain bulk and thin film samples.
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	39
http://linked.open...iv/tvurceVysledku	Dušek, Michal Fejfarová, Karla Khalaji, A. D. Rezaei, M. Grivan, G.
http://linked.open...ain/vavai/riv/wos	000312907700017
http://linked.open...n/vavai/riv/zamer	Physics and technology of nanostructures, surfaces and thin films
issn	1070-3284
number of pages	5 (xsd:int)
http://bibframe.org/vocab/doi	10.1134/S1070328412100077

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