About: Diiodo{N,N´-bis(2,3,4-trimethoxybenzaldehyde)-ethylenediimine}mercury(II): synthesis and crystal structure     Goto   Sponge   NotDistinct   Permalink

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Description
  • Mononuclear mercury(II) complex [Hg((2,3,4-MeO-Ba)2En)I2], where (2,3,4-MeO-Ba)2En =N,N'-bis(2,3,4-trimethoxybenzaldehyde)ethylenediimine, has been synthesized and characterized by elemental analysis (C, H, and N) and confirmed by single-crystal X-ray diffraction analysis. The complex crystallizes in the monoclinic system, with space group C2/c, having one symmetry-independent Hg2+ ion coordinated in distorted tetrahedral geometry by two N atoms of the Schiff base ligand and by two I atoms. The Schiff base ligand (2,3,4-MeO-Ba)-22En acts as a chelating ligand and coordinates via two N atoms to the mercury center.
  • Mononuclear mercury(II) complex [Hg((2,3,4-MeO-Ba)2En)I2], where (2,3,4-MeO-Ba)2En =N,N'-bis(2,3,4-trimethoxybenzaldehyde)ethylenediimine, has been synthesized and characterized by elemental analysis (C, H, and N) and confirmed by single-crystal X-ray diffraction analysis. The complex crystallizes in the monoclinic system, with space group C2/c, having one symmetry-independent Hg2+ ion coordinated in distorted tetrahedral geometry by two N atoms of the Schiff base ligand and by two I atoms. The Schiff base ligand (2,3,4-MeO-Ba)-22En acts as a chelating ligand and coordinates via two N atoms to the mercury center. (en)
Title
  • Diiodo{N,N´-bis(2,3,4-trimethoxybenzaldehyde)-ethylenediimine}mercury(II): synthesis and crystal structure
  • Diiodo{N,N´-bis(2,3,4-trimethoxybenzaldehyde)-ethylenediimine}mercury(II): synthesis and crystal structure (en)
skos:prefLabel
  • Diiodo{N,N´-bis(2,3,4-trimethoxybenzaldehyde)-ethylenediimine}mercury(II): synthesis and crystal structure
  • Diiodo{N,N´-bis(2,3,4-trimethoxybenzaldehyde)-ethylenediimine}mercury(II): synthesis and crystal structure (en)
skos:notation
  • RIV/68378271:_____/13:00391677!RIV14-AV0-68378271
http://linked.open...avai/riv/aktivita
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  • I
http://linked.open...iv/cisloPeriodika
  • 1
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  • 69735
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  • RIV/68378271:_____/13:00391677
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  • mercury (II); Schiff base; single crystal; structure analysis (en)
http://linked.open.../riv/klicoveSlovo
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  • RU - Ruská federace
http://linked.open...ontrolniKodProRIV
  • [016363C873F8]
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  • Russian Journal of Coordination Chemistry
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  • 39
http://linked.open...iv/tvurceVysledku
  • Dušek, Michal
  • Fejfarová, Karla
  • Khalaji, A. D.
http://linked.open...ain/vavai/riv/wos
  • 000312907700011
issn
  • 1070-3284
number of pages
http://bibframe.org/vocab/doi
  • 10.1134/S1070328412090047
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