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  • The glass-forming region of the ZnO–WO3-P2O5 system has been determined and basic physical properties of the glasses were obtained. Structure and properties of these glasses were studied by Raman and 31P NMR spectroscopies. 31P MAS NMR spectra of the glasses show that the phosphate chains are shortened by the incorporation of tungstate structural units. The co-existence of WO4 and WO6 units in the glass structure was seen in glasses with a high ZnO content. Raman spectra reveal existence of isolated WO6 units especially in the glasses with a low WO3 content and a high P2O5 content. Clustering of WO6 units by the formation W–O–W bonds takes place in glasses with high WO3 content.
  • The glass-forming region of the ZnO–WO3-P2O5 system has been determined and basic physical properties of the glasses were obtained. Structure and properties of these glasses were studied by Raman and 31P NMR spectroscopies. 31P MAS NMR spectra of the glasses show that the phosphate chains are shortened by the incorporation of tungstate structural units. The co-existence of WO4 and WO6 units in the glass structure was seen in glasses with a high ZnO content. Raman spectra reveal existence of isolated WO6 units especially in the glasses with a low WO3 content and a high P2O5 content. Clustering of WO6 units by the formation W–O–W bonds takes place in glasses with high WO3 content. (en)
Title
  • Glass-forming ability and structure of glasses in the ZnO-WO3-P2O5 system
  • Glass-forming ability and structure of glasses in the ZnO-WO3-P2O5 system (en)
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  • Glass-forming ability and structure of glasses in the ZnO-WO3-P2O5 system
  • Glass-forming ability and structure of glasses in the ZnO-WO3-P2O5 system (en)
skos:notation
  • RIV/68378271:_____/12:00380606!RIV13-AV0-68378271
http://linked.open...avai/riv/aktivita
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  • P(KAN301370701), Z(AV0Z10100520)
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  • 3
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  • 138184
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  • RIV/68378271:_____/12:00380606
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  • glasses; ternary systems; Raman spectra; NMR (en)
http://linked.open.../riv/klicoveSlovo
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [E3F63F803A91]
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  • European Journal of Glass Science and Techology. Part B. Physics and Chemistry of Glasses
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  • 53
http://linked.open...iv/tvurceVysledku
  • Gregora, Ivan
  • Delevoye, L.
  • Koudelka, L.
  • Montagne, L.
  • Mošner, P.
  • Šubčík, J.
http://linked.open...ain/vavai/riv/wos
  • 000308900000004
http://linked.open...n/vavai/riv/zamer
issn
  • 1753-3562
number of pages
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