About: Luminescence and decay kinetic mechanism of Pr3+ centre in Lu0.8Sc0.2BO3 host     Goto   Sponge   NotDistinct   Permalink

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  • The optical absorption, temperature dependence of emission spectra, prompt nanosecond decays and milisecond delayed recombination decays for Pr3+ centre in Lu0.8Sc0.2BO3 host were studied. The photoluminescence decay time decreases from 16 ns (80 K) to 11 ns (300 K), but its steady-state emission intensity at 300 K is stronger than that at 80 K and towards higher temperatures is further decreasing comparatively much less with respect to the decay time shortening. This abnormal phenomenon was proved to be associated with the thermal ionization processes occurring from 5d1 relaxed state of Pr3+ by slow decay measurement. The quantitative parameters, activation energy and frequency factor, governing the ionization processes, were calculated by the single escape barrier kinetic model.
  • The optical absorption, temperature dependence of emission spectra, prompt nanosecond decays and milisecond delayed recombination decays for Pr3+ centre in Lu0.8Sc0.2BO3 host were studied. The photoluminescence decay time decreases from 16 ns (80 K) to 11 ns (300 K), but its steady-state emission intensity at 300 K is stronger than that at 80 K and towards higher temperatures is further decreasing comparatively much less with respect to the decay time shortening. This abnormal phenomenon was proved to be associated with the thermal ionization processes occurring from 5d1 relaxed state of Pr3+ by slow decay measurement. The quantitative parameters, activation energy and frequency factor, governing the ionization processes, were calculated by the single escape barrier kinetic model. (en)
Title
  • Luminescence and decay kinetic mechanism of Pr3+ centre in Lu0.8Sc0.2BO3 host
  • Luminescence and decay kinetic mechanism of Pr3+ centre in Lu0.8Sc0.2BO3 host (en)
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  • Luminescence and decay kinetic mechanism of Pr3+ centre in Lu0.8Sc0.2BO3 host
  • Luminescence and decay kinetic mechanism of Pr3+ centre in Lu0.8Sc0.2BO3 host (en)
skos:notation
  • RIV/68378271:_____/12:00379870!RIV13-AV0-68378271
http://linked.open...avai/riv/aktivita
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  • P(LH12185), Z(AV0Z10100521)
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  • JUN
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  • 147580
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  • RIV/68378271:_____/12:00379870
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  • borate; luminescence; excited state ionization; Pr3+; decay kinetics (en)
http://linked.open.../riv/klicoveSlovo
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  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [E15656A96A3D]
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  • Chemical Physics Letters
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  • 539-540
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  • Nikl, Martin
  • Jarý, Vítězslav
  • Ren, G.
  • Wu, Y.
  • Ding, D.
  • Pan, S.
  • Yang, F.
http://linked.open...ain/vavai/riv/wos
  • 000305802600008
http://linked.open...n/vavai/riv/zamer
issn
  • 0009-2614
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.cplett.2012.05.010
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