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  • CuIn1xAlxS2 thin films (x = 0, 0.09, 0.27, 0.46, 0.64, 0.82 and 1) with thicknesses of approximately 1 μm were formed by the sulfurization of DC sputtered Cu–In–Al precursors. All samples were sulfurized in a graphite container for 90 min at 650 °C in a 150 kPa Ar + S atmosphere. Final films were studied via X-ray diffraction (XRD), scanning electron microscopy (SEM) and micro-Raman spectroscopy. It was found that all samples were polycrystalline in nature and their lattice parameters varied slightly nonlinearly from {a = 5.49 Å, c = 11.02 Å} for CuInS2 to {a = 5.30 Å, c = 10.36 Å} for CuAlS2. No unwanted phases such as Cu2xS or others were observed. Raman were recorded at a room temperature and the most intensive and dominant A1 phonon frequency varied nonlinearly from 294 cm1 (CuInS2) to 314 cm1 (CuAlS2).
  • CuIn1xAlxS2 thin films (x = 0, 0.09, 0.27, 0.46, 0.64, 0.82 and 1) with thicknesses of approximately 1 μm were formed by the sulfurization of DC sputtered Cu–In–Al precursors. All samples were sulfurized in a graphite container for 90 min at 650 °C in a 150 kPa Ar + S atmosphere. Final films were studied via X-ray diffraction (XRD), scanning electron microscopy (SEM) and micro-Raman spectroscopy. It was found that all samples were polycrystalline in nature and their lattice parameters varied slightly nonlinearly from {a = 5.49 Å, c = 11.02 Å} for CuInS2 to {a = 5.30 Å, c = 10.36 Å} for CuAlS2. No unwanted phases such as Cu2xS or others were observed. Raman were recorded at a room temperature and the most intensive and dominant A1 phonon frequency varied nonlinearly from 294 cm1 (CuInS2) to 314 cm1 (CuAlS2). (en)
Title
  • CuIn1xAlxS2 thin films prepared by sulfurization of metallic precursors
  • CuIn1xAlxS2 thin films prepared by sulfurization of metallic precursors (en)
skos:prefLabel
  • CuIn1xAlxS2 thin films prepared by sulfurization of metallic precursors
  • CuIn1xAlxS2 thin films prepared by sulfurization of metallic precursors (en)
skos:notation
  • RIV/68378271:_____/11:00375572!RIV12-AV0-68378271
http://linked.open...avai/riv/aktivita
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  • Z(AV0Z10100522)
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  • 41
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  • 192448
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  • RIV/68378271:_____/11:00375572
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  • CuIn1xAlxS2; CIAS; chalcopyrites; Raman spectroscopy; solar cells (en)
http://linked.open.../riv/klicoveSlovo
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  • NL - Nizozemsko
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  • [77C91A8AA7AC]
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  • Journal of Alloys and Compounds
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 509
http://linked.open...iv/tvurceVysledku
  • Darveau, S. A.
  • Exstrom, C. L.
  • Flannery, L. E.
  • Ianno, N. J.
  • Kment, Štěpán
  • Olejníček, Jiří
  • Soukup, R. J.
http://linked.open...ain/vavai/riv/wos
  • 000295978500050
http://linked.open...n/vavai/riv/zamer
issn
  • 0925-8388
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.jallcom.2011.08.016
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