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  • In DyMnO3 orthorhombic single crystals,the weak Raman active phonon softening below T=100 K is correlated with the study of infrared active Dy3+ CF excitations as a function of temperature and under applied magnetic field.We detect five H13/2 CF transitions that we predict with appropriate CF Hamiltonian and we confirm that the magnetic easy axis lies in the ab plane.While the CF energy level shifts below T=100 K reflect different displacements of the oxygen ions that contribute to the phonon softening,lifting of the ground state Kramers doublet degeneracy(30 cm-1) is observed below TN=39 K due to the anisotropic Mn3+-Dy3+ interaction, which could be responsible for the stability of the bc-cycloid ferroelectric phase.
  • In DyMnO3 orthorhombic single crystals,the weak Raman active phonon softening below T=100 K is correlated with the study of infrared active Dy3+ CF excitations as a function of temperature and under applied magnetic field.We detect five H13/2 CF transitions that we predict with appropriate CF Hamiltonian and we confirm that the magnetic easy axis lies in the ab plane.While the CF energy level shifts below T=100 K reflect different displacements of the oxygen ions that contribute to the phonon softening,lifting of the ground state Kramers doublet degeneracy(30 cm-1) is observed below TN=39 K due to the anisotropic Mn3+-Dy3+ interaction, which could be responsible for the stability of the bc-cycloid ferroelectric phase. (en)
Title
  • Study of crystal-field excitations and Raman active phonons in o-DyMnO3.
  • Study of crystal-field excitations and Raman active phonons in o-DyMnO3. (en)
skos:prefLabel
  • Study of crystal-field excitations and Raman active phonons in o-DyMnO3.
  • Study of crystal-field excitations and Raman active phonons in o-DyMnO3. (en)
skos:notation
  • RIV/68378271:_____/11:00371415!RIV12-AV0-68378271
http://linked.open...avai/riv/aktivita
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  • P(IAA100100803), Z(AV0Z10100521)
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  • 8
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  • 233049
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  • RIV/68378271:_____/11:00371415
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  • manganite; multiferroic; Raman active phonons; crystal fields (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [BD2FDB0D4E31]
http://linked.open...i/riv/nazevZdroje
  • Journal of Magnetism and Magnetic Materials
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http://linked.open...v/svazekPeriodika
  • 323
http://linked.open...iv/tvurceVysledku
  • Orlita, Milan
  • Balbashov, A.
  • Gospodino, M. M.
  • Ivanov, V. Yu.
  • Jandl, S.
  • Mansouri, S.
  • Mukhin, A. A.
  • Nekvasil, Vladimír
http://linked.open...ain/vavai/riv/wos
  • 000286197000012
http://linked.open...n/vavai/riv/zamer
issn
  • 0304-8853
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.jmmm.2010.12.031
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