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  • We have investigated the magnetic response of residual metal catalyst in the raw and super purified HiPco single wall carbon nanotubes (HiPco_raw and HiPco_SPSWCNTs). It has been shown that the residual metal catalyst is in the form of nanoparticles, even in the HiPco_SP SWCNTs that should contain a minimal amount of the metal. Moessbauer spectroscopy of the HiPco_raw SWCNTs proved the catalyst nanoparticles are in the form of Fe3C. Analysis of the synchrotron X-ray diffraction data provided an average diameter of nanoparticles about 1.9 nm. Magnetic studies by means of temperature dependence of magnetization, magnetization isotherms and susceptibility suggested that the nanoparticles obey the behavior of weakly interacting superparamagnetic systems in both samples.
  • We have investigated the magnetic response of residual metal catalyst in the raw and super purified HiPco single wall carbon nanotubes (HiPco_raw and HiPco_SPSWCNTs). It has been shown that the residual metal catalyst is in the form of nanoparticles, even in the HiPco_SP SWCNTs that should contain a minimal amount of the metal. Moessbauer spectroscopy of the HiPco_raw SWCNTs proved the catalyst nanoparticles are in the form of Fe3C. Analysis of the synchrotron X-ray diffraction data provided an average diameter of nanoparticles about 1.9 nm. Magnetic studies by means of temperature dependence of magnetization, magnetization isotherms and susceptibility suggested that the nanoparticles obey the behavior of weakly interacting superparamagnetic systems in both samples. (en)
Title
  • Magnetic properties of iron catalyst particles in HiPco single wall carbon nanotubes
  • Magnetic properties of iron catalyst particles in HiPco single wall carbon nanotubes (en)
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  • Magnetic properties of iron catalyst particles in HiPco single wall carbon nanotubes
  • Magnetic properties of iron catalyst particles in HiPco single wall carbon nanotubes (en)
skos:notation
  • RIV/68378271:_____/11:00367520!RIV12-AV0-68378271
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GAP204/10/1677), Z(AV0Z10100520), Z(AV0Z40400503), Z(MSM0021620834)
http://linked.open...iv/cisloPeriodika
  • 35
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  • 210225
http://linked.open...ai/riv/idVysledku
  • RIV/68378271:_____/11:00367520
http://linked.open...riv/jazykVysledku
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  • metal catalyst particles; carbon nanotubes; superparamagnet; core-shell model; inter-particle interactions (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [B0D7EC1472E2]
http://linked.open...i/riv/nazevZdroje
  • Journal of Physical Chemistry C
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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  • 115
http://linked.open...iv/tvurceVysledku
  • Kalbáč, Martin
  • Poltierová Vejpravová, Jana
  • Bittová, Barbara
  • Burianová, Simona
  • Daniš, S.
  • Doyle, S.
  • Mantlíková, A.
http://linked.open...ain/vavai/riv/wos
  • 000294386000010
http://linked.open...n/vavai/riv/zamer
issn
  • 1932-7447
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/jp203365g
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