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  • Previous high-resolution x-ray powder diffraction and transmission electron microscopy studies of the zeolite SSZ-57 could not fully elucidate the structural basis for its puzzling adsorption behavior, which appears to be intermediate between that of a medium- (10-ring) and a large-pore (12-ring) zeolite. Now by applying advanced crystallographic techniques and crystal chemistry considerations to high-quality single-crystal x-ray diffraction data collected on a microcrystal (about 2 micrometers by 2 micrometers by 8 micrometers), we have been able to derive a comprehensive description of its silicate framework structure.The framework is related to that of ZSM-11 but is commensurately modulated along the c axis to yield a structure with a 12-ring:10-ring ratio of 1:15. Disorder of the 12-rings results in a three-dimensional 10-ring channel system with large isolated pockets. The structure helps to clarify the material´s catalytic activity.
  • Previous high-resolution x-ray powder diffraction and transmission electron microscopy studies of the zeolite SSZ-57 could not fully elucidate the structural basis for its puzzling adsorption behavior, which appears to be intermediate between that of a medium- (10-ring) and a large-pore (12-ring) zeolite. Now by applying advanced crystallographic techniques and crystal chemistry considerations to high-quality single-crystal x-ray diffraction data collected on a microcrystal (about 2 micrometers by 2 micrometers by 8 micrometers), we have been able to derive a comprehensive description of its silicate framework structure.The framework is related to that of ZSM-11 but is commensurately modulated along the c axis to yield a structure with a 12-ring:10-ring ratio of 1:15. Disorder of the 12-rings results in a three-dimensional 10-ring channel system with large isolated pockets. The structure helps to clarify the material´s catalytic activity. (en)
Title
  • Unraveling the perplexing structure of the zeolite SSZ-57
  • Unraveling the perplexing structure of the zeolite SSZ-57 (en)
skos:prefLabel
  • Unraveling the perplexing structure of the zeolite SSZ-57
  • Unraveling the perplexing structure of the zeolite SSZ-57 (en)
skos:notation
  • RIV/68378271:_____/11:00365564!RIV12-AV0-68378271
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z10100521)
http://linked.open...iv/cisloPeriodika
  • 6046
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 236904
http://linked.open...ai/riv/idVysledku
  • RIV/68378271:_____/11:00365564
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • zeolite; disorder; superspace; Monte Carlo simulation; diffuse scattering (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [CC1AC7F840ED]
http://linked.open...i/riv/nazevZdroje
  • Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 333
http://linked.open...iv/tvurceVysledku
  • Palatinus, Lukáš
  • Weber, T.
  • Baerlocher, Ch.
  • McCusker, L. B.
  • Zones, S. I.
http://linked.open...ain/vavai/riv/wos
  • 000294244300045
http://linked.open...n/vavai/riv/zamer
issn
  • 0036-8075
number of pages
http://bibframe.org/vocab/doi
  • 10.1126/science.1207466
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