About: Structure determination and compositional modification of body-centered tetragonal PX-phase lead titanate     Goto   Sponge   NotDistinct   Permalink

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  • Fibrous PX-phase of lead titanate was studied to clarify its structural aspects. Combining X-ray diffraction and electron microscope analysis with a first-principles calculation, a unique open channel wire-like structure with a 5.53 A is determined. PX-phase structture was shown to have a wide indirect gap. Frequency and symmetry of Raman-active lattice vibration modes have been identified in polarized Raman spectra and a good match with calculations was found. Doping with Zr of the PX-phase PT was also investigated, showing a limit of 17% incorporation.
  • Fibrous PX-phase of lead titanate was studied to clarify its structural aspects. Combining X-ray diffraction and electron microscope analysis with a first-principles calculation, a unique open channel wire-like structure with a 5.53 A is determined. PX-phase structture was shown to have a wide indirect gap. Frequency and symmetry of Raman-active lattice vibration modes have been identified in polarized Raman spectra and a good match with calculations was found. Doping with Zr of the PX-phase PT was also investigated, showing a limit of 17% incorporation. (en)
Title
  • Structure determination and compositional modification of body-centered tetragonal PX-phase lead titanate
  • Structure determination and compositional modification of body-centered tetragonal PX-phase lead titanate (en)
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  • Structure determination and compositional modification of body-centered tetragonal PX-phase lead titanate
  • Structure determination and compositional modification of body-centered tetragonal PX-phase lead titanate (en)
skos:notation
  • RIV/68378271:_____/11:00365288!RIV12-AV0-68378271
http://linked.open...avai/riv/aktivita
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  • P(KAN301370701), Z(AV0Z10100520)
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  • 10
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  • 232799
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  • RIV/68378271:_____/11:00365288
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  • lead titanate; fibrous PX phase; structure determination; open channels; Raman scattering (en)
http://linked.open.../riv/klicoveSlovo
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  • US - Spojené státy americké
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  • [A565BBD9B70D]
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  • Chemistry of Materials
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  • 23
http://linked.open...iv/tvurceVysledku
  • Wang, J.
  • Gregora, Ivan
  • Setter, N.
  • Bonin, M.
  • Briddon, P. R.
  • Carvalho, A.
  • Funakubo, H.
  • He, Z.
  • Sandu, C. S.
  • Schenk, K.
  • Trodahl, J.
  • Wylie-van Eerd, B.
  • Yamada, T.
http://linked.open...ain/vavai/riv/wos
  • 000290594700006
http://linked.open...n/vavai/riv/zamer
issn
  • 0897-4756
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/cm1030206
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