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  • Thermoelectric properties of the Mo2.57Fe0.43Sb7 compound, a ternary derivative of Mo3Sb7, are reported from 2 up to 1000 K. Even though Fe substitution keeps low electrical resistivity values,high thermopower values are achieved at high temperatures. Electronic band structure calculations show that the high thermopower observed arises from the beneficial influence of iron d-states contribution to the density of states at the Fermi level. A high power factor similar to those of the best state-of-the-art thermoelectric materials emerges which, coupled with magnetic excitations that help to keep very low thermal conductivity values, leads to a dimensionless thermoelectric figure of merit of 0.55 at 1000 K.
  • Thermoelectric properties of the Mo2.57Fe0.43Sb7 compound, a ternary derivative of Mo3Sb7, are reported from 2 up to 1000 K. Even though Fe substitution keeps low electrical resistivity values,high thermopower values are achieved at high temperatures. Electronic band structure calculations show that the high thermopower observed arises from the beneficial influence of iron d-states contribution to the density of states at the Fermi level. A high power factor similar to those of the best state-of-the-art thermoelectric materials emerges which, coupled with magnetic excitations that help to keep very low thermal conductivity values, leads to a dimensionless thermoelectric figure of merit of 0.55 at 1000 K. (en)
Title
  • High thermoelectric power factor in Fe-substituted Mo3Sb7.
  • High thermoelectric power factor in Fe-substituted Mo3Sb7. (en)
skos:prefLabel
  • High thermoelectric power factor in Fe-substituted Mo3Sb7.
  • High thermoelectric power factor in Fe-substituted Mo3Sb7. (en)
skos:notation
  • RIV/68378271:_____/10:00352410!RIV11-GA0-68378271
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/09/1036), Z(AV0Z10100521)
http://linked.open...iv/cisloPeriodika
  • 26
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
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  • 261540
http://linked.open...ai/riv/idVysledku
  • RIV/68378271:_____/10:00352410
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • antimony alloys; band structure; chemical exchanges; electrical resistivity; electronic density of states; electronic structure; Fermi level (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [5F99E585A597]
http://linked.open...i/riv/nazevZdroje
  • Applied Physics Letters
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 96
http://linked.open...iv/tvurceVysledku
  • Hejtmánek, Jiří
  • Candolfi, C.
  • Dauscher, A.
  • Lenoir, B.
  • Tobola, J.
  • Guilmeau, E.
  • Malaman, B.
http://linked.open...ain/vavai/riv/wos
  • 000279514400023
http://linked.open...n/vavai/riv/zamer
issn
  • 0003-6951
number of pages
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