About: Metal-dependent assembly of a tetranuclear copper(II) complex versus a 1D chain coordination polymer of cobalt(III) complex with N2O2-chelating Schiff-base ligand: Synthesis, characterization and crystal structures

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About: Metal-dependent assembly of a tetranuclear copper(II) complex versus a 1D chain coordination polymer of cobalt(III) complex with N2O2-chelating Schiff-base ligand: Synthesis, characterization and crystal structures Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	By changing metal ions in the presence of N2O2-chelating Schiff-base ligand sal2hn [sal2hn = N,N'-bis(salicylidene)-1,2-diaminocyclohexane] and a large excess of NaN3, tetranuclear copper(II) complex [Cu4(μ-sal2hn)2(μ1,1-N3)2(N3)2] (1) and 1D chain coordination polymer of cobalt(III) complex {Na[Co(μ-sal2hn)(μ1,1-N3)(N3)(H2O)(μ-O)}n(2) have been successfully obtained. Single-crystal X-ray analyses revealed that in complex 1 the copper(II) ions are bridged alternately by azido and phenoxo-sal2hn ligands, while in complex 2 the cobalt(III) and sodium ions are bridged alternately by azido and phenoxo-sal2hn ligands and sodium ions are linked together by O atoms to form polymeric chain. By changing metal ions in the presence of N2O2-chelating Schiff-base ligand sal2hn [sal2hn = N,N'-bis(salicylidene)-1,2-diaminocyclohexane] and a large excess of NaN3, tetranuclear copper(II) complex [Cu4(μ-sal2hn)2(μ1,1-N3)2(N3)2] (1) and 1D chain coordination polymer of cobalt(III) complex {Na[Co(μ-sal2hn)(μ1,1-N3)(N3)(H2O)(μ-O)}n(2) have been successfully obtained. Single-crystal X-ray analyses revealed that in complex 1 the copper(II) ions are bridged alternately by azido and phenoxo-sal2hn ligands, while in complex 2 the cobalt(III) and sodium ions are bridged alternately by azido and phenoxo-sal2hn ligands and sodium ions are linked together by O atoms to form polymeric chain. (en)
Title	Metal-dependent assembly of a tetranuclear copper(II) complex versus a 1D chain coordination polymer of cobalt(III) complex with N2O2-chelating Schiff-base ligand: Synthesis, characterization and crystal structures Metal-dependent assembly of a tetranuclear copper(II) complex versus a 1D chain coordination polymer of cobalt(III) complex with N2O2-chelating Schiff-base ligand: Synthesis, characterization and crystal structures (en)
skos:prefLabel	Metal-dependent assembly of a tetranuclear copper(II) complex versus a 1D chain coordination polymer of cobalt(III) complex with N2O2-chelating Schiff-base ligand: Synthesis, characterization and crystal structures Metal-dependent assembly of a tetranuclear copper(II) complex versus a 1D chain coordination polymer of cobalt(III) complex with N2O2-chelating Schiff-base ligand: Synthesis, characterization and crystal structures (en)
skos:notation	RIV/68378271:_____/10:00348567!RIV11-AV0-68378271
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(AV0Z10100521)
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Fejfarová, Karla Dušek, Michal
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Fyzikální ústav AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	270605
http://linked.open...ai/riv/idVysledku	RIV/68378271:_____/10:00348567
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Schiff bases; crystal structure; Jana2006; coordination chemistry (en)
http://linked.open.../riv/klicoveSlovo	Jana2006 crystal structure Schiff bases coordination chemistry
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[B4863F5D0483]
http://linked.open...i/riv/nazevZdroje	Polyhedron
http://linked.open...in/vavai/riv/obor	BM
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	29
http://linked.open...iv/tvurceVysledku	Dušek, Michal Fejfarová, Karla Khalaji, A. D. Hadadzadeh, H.
http://linked.open...ain/vavai/riv/wos	000275020700019
http://linked.open...n/vavai/riv/zamer	Physics and technology of nanostructures, surfaces and thin films
issn	0277-5387
number of pages	6 (xsd:int)

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