About: Second harmonic generation and dielectric study of the fine and coarse grain PMN-35PT ceramics     Goto   Sponge   NotDistinct   Permalink

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  • We investigated the grain size effect on the high temperature behaviour of PMN-35PT ceramics around the tetragonal–cubic phase transition using second harmonic generation (SHG) and dielectric spectroscopy. Our data revealed coexistence of the first-order ferroelectric phase transition and relaxor behaviour in the coarse grain (grain size 4 μm) μ_PMN-35PT. The phase transition is hindered and relaxor features prevail in the fine grain (grain size 150 nm) n_PMN-35PT ceramics. Effect of the grain-size reduction on the SHG and dielectric response could be attributed to stabilisation of intermediate domain configurations between the frozen polar nanoclusters and large ferroelectric domains and to the enhanced stability of polar nanoclusters in the fine grain ceramics.
  • We investigated the grain size effect on the high temperature behaviour of PMN-35PT ceramics around the tetragonal–cubic phase transition using second harmonic generation (SHG) and dielectric spectroscopy. Our data revealed coexistence of the first-order ferroelectric phase transition and relaxor behaviour in the coarse grain (grain size 4 μm) μ_PMN-35PT. The phase transition is hindered and relaxor features prevail in the fine grain (grain size 150 nm) n_PMN-35PT ceramics. Effect of the grain-size reduction on the SHG and dielectric response could be attributed to stabilisation of intermediate domain configurations between the frozen polar nanoclusters and large ferroelectric domains and to the enhanced stability of polar nanoclusters in the fine grain ceramics. (en)
  • Byl studován efekt velikosti zrn na vysokoteplotní chování PMN-35PT keramiky v okolí fázového přechodu z tetragonální do kubické fáze pomocí generace druhé harmonické (SHG) a dielektrické spektroskopie. Měření potvrdila koexistenci feroelektrického a relaxorového chování v keramice s hrubým zrnem (rozměru 4 μm), zatímco u jemnozrnné keramiky (zrna 150 nm) převažuje relaxorové chování a fázový přechod probíha spojitě, v souvislosti se zvýšenou stabilizace polárních nanoklastrů v jemnozrnné keramice. (cs)
Title
  • Second harmonic generation and dielectric study of the fine and coarse grain PMN-35PT ceramics
  • Second harmonic generation and dielectric study of the fine and coarse grain PMN-35PT ceramics (en)
  • Studium jemno- a hrubozrnné keramiky PMN-35PT pomocí SHG a dielektrických měřen (cs)
skos:prefLabel
  • Second harmonic generation and dielectric study of the fine and coarse grain PMN-35PT ceramics
  • Second harmonic generation and dielectric study of the fine and coarse grain PMN-35PT ceramics (en)
  • Studium jemno- a hrubozrnné keramiky PMN-35PT pomocí SHG a dielektrických měřen (cs)
skos:notation
  • RIV/68378271:_____/08:00320797!RIV09-AV0-68378271
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA202/06/0403), P(OC 101), Z(AV0Z10100520)
http://linked.open...iv/cisloPeriodika
  • 11-12
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 394008
http://linked.open...ai/riv/idVysledku
  • RIV/68378271:_____/08:00320797
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • relaxor ferroelectrics; phase transitions; PMN-PT; SHG; dielectric (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [B8422DC84D77]
http://linked.open...i/riv/nazevZdroje
  • Phase Transitions
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 81
http://linked.open...iv/tvurceVysledku
  • Bovtun, Viktor
  • Kosec, M.
  • Kamba, Stanislav
  • Vaněk, Přemysl
  • Petzelt, Jan
  • Savinov, Maxim
  • Kroupa, Jan
  • Noujni, Dmitri
  • Alguero, M.
  • Amorin, H.
  • Holc, J.
http://linked.open...ain/vavai/riv/wos
  • 000261661300012
http://linked.open...n/vavai/riv/zamer
issn
  • 0141-1594
number of pages
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